Macrocyclic anion receptors based on directed hydrogen bonding interactions

Kihang Choi; Andrew D. Hamilton

doi:10.1016/s0010-8545(02)00305-3

Macrocyclic anion receptors based on directed hydrogen bonding interactions

Kihang Choi, Andrew D. Hamilton

Research output: Contribution to journal › Review article › peer-review

382 Citations (Scopus)

Abstract

Natural anion receptors use charge-neutral dipoles to bind small anions with high affinities and selectivities. A convergent and rigid display of hydrogen bond donors such as amide, thiourea and urea functional groups in macrocyclic scaffolds would be one of the most efficient ways to create synthetic anion receptors that mimic natural ones. In this article, we present examples of natural anion receptors and discuss the synthesis of neutral macrocyclic receptors and their anion binding properties.

Original language	English
Pages (from-to)	101-110
Number of pages	10
Journal	Coordination Chemistry Reviews
Volume	240
Issue number	1-2
DOIs	https://doi.org/10.1016/s0010-8545(02)00305-3
Publication status	Published - 2003 May
Externally published	Yes

Bibliographical note

Funding Information:
We thank the National Institutes of Health (GM35208) for financial support of the work described in this review that was carried out at Yale.

Keywords

Anion binding
Macrocycles
Supramolecular chemistry

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/s0010-8545(02)00305-3

Cite this

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abstract = "Natural anion receptors use charge-neutral dipoles to bind small anions with high affinities and selectivities. A convergent and rigid display of hydrogen bond donors such as amide, thiourea and urea functional groups in macrocyclic scaffolds would be one of the most efficient ways to create synthetic anion receptors that mimic natural ones. In this article, we present examples of natural anion receptors and discuss the synthesis of neutral macrocyclic receptors and their anion binding properties.",

keywords = "Anion binding, Macrocycles, Supramolecular chemistry",

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AU - Hamilton, Andrew D.

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PY - 2003/5

Y1 - 2003/5

N2 - Natural anion receptors use charge-neutral dipoles to bind small anions with high affinities and selectivities. A convergent and rigid display of hydrogen bond donors such as amide, thiourea and urea functional groups in macrocyclic scaffolds would be one of the most efficient ways to create synthetic anion receptors that mimic natural ones. In this article, we present examples of natural anion receptors and discuss the synthesis of neutral macrocyclic receptors and their anion binding properties.

AB - Natural anion receptors use charge-neutral dipoles to bind small anions with high affinities and selectivities. A convergent and rigid display of hydrogen bond donors such as amide, thiourea and urea functional groups in macrocyclic scaffolds would be one of the most efficient ways to create synthetic anion receptors that mimic natural ones. In this article, we present examples of natural anion receptors and discuss the synthesis of neutral macrocyclic receptors and their anion binding properties.

KW - Anion binding

KW - Macrocycles

KW - Supramolecular chemistry

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U2 - 10.1016/s0010-8545(02)00305-3

DO - 10.1016/s0010-8545(02)00305-3

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ER -

Macrocyclic anion receptors based on directed hydrogen bonding interactions

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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Cite this