Mechanistic insights into oxidative decomposition of exo- tetrahydrodicyclopentadiene

Sun Hee Park; Cheong Hoon Kwon; Joongyeon Kim; Jeong Sik Han; Byung Hun Jeong; Hogyu Han; Sung Hyun Kim

doi:10.1021/jp404730g

Mechanistic insights into oxidative decomposition of exo- tetrahydrodicyclopentadiene

Sun Hee Park, Cheong Hoon Kwon, Joongyeon Kim, Jeong Sik Han, Byung Hun Jeong, Hogyu Han, Sung Hyun Kim

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

We investigated the decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C₁₀H₁₆) in the absence and presence of O ₂ at various temperatures. It was found that conversion of exo-THDCP was faster in the presence of O₂ as compared to in its absence. The O₂-induced increase in the conversion of exo-THDCP was hardly affected by variations in temperature. In addition, the O₂-induced increase in the rate of C₁₀ product formation was higher than those of <C₁₀ and >C₁₀. We proposed the mechanism for the oxidative decomposition of exo-THDCP, which occurs independently of its thermal decomposition and induces distinct product formation near and below its thermal decomposition starting temperature.

Original language	English
Pages (from-to)	15933-15939
Number of pages	7
Journal	Journal of Physical Chemistry C
Volume	117
Issue number	31
DOIs	https://doi.org/10.1021/jp404730g
Publication status	Published - 2013 Aug 8

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Energy(all)
Physical and Theoretical Chemistry
Surfaces, Coatings and Films

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title = "Mechanistic insights into oxidative decomposition of exo- tetrahydrodicyclopentadiene",

abstract = "We investigated the decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of O 2 at various temperatures. It was found that conversion of exo-THDCP was faster in the presence of O2 as compared to in its absence. The O2-induced increase in the conversion of exo-THDCP was hardly affected by variations in temperature. In addition, the O2-induced increase in the rate of C10 product formation was higher than those of <C10 and >C10. We proposed the mechanism for the oxidative decomposition of exo-THDCP, which occurs independently of its thermal decomposition and induces distinct product formation near and below its thermal decomposition starting temperature.",

author = "Park, {Sun Hee} and Kwon, {Cheong Hoon} and Joongyeon Kim and Han, {Jeong Sik} and Jeong, {Byung Hun} and Hogyu Han and Kim, {Sung Hyun}",

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AU - Park, Sun Hee

AU - Kwon, Cheong Hoon

AU - Kim, Joongyeon

AU - Han, Jeong Sik

AU - Jeong, Byung Hun

AU - Han, Hogyu

AU - Kim, Sung Hyun

PY - 2013/8/8

Y1 - 2013/8/8

N2 - We investigated the decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of O 2 at various temperatures. It was found that conversion of exo-THDCP was faster in the presence of O2 as compared to in its absence. The O2-induced increase in the conversion of exo-THDCP was hardly affected by variations in temperature. In addition, the O2-induced increase in the rate of C10 product formation was higher than those of <C10 and >C10. We proposed the mechanism for the oxidative decomposition of exo-THDCP, which occurs independently of its thermal decomposition and induces distinct product formation near and below its thermal decomposition starting temperature.

AB - We investigated the decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of O 2 at various temperatures. It was found that conversion of exo-THDCP was faster in the presence of O2 as compared to in its absence. The O2-induced increase in the conversion of exo-THDCP was hardly affected by variations in temperature. In addition, the O2-induced increase in the rate of C10 product formation was higher than those of <C10 and >C10. We proposed the mechanism for the oxidative decomposition of exo-THDCP, which occurs independently of its thermal decomposition and induces distinct product formation near and below its thermal decomposition starting temperature.

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DO - 10.1021/jp404730g

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JO - Journal of Physical Chemistry C

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ER -

Mechanistic insights into oxidative decomposition of exo- tetrahydrodicyclopentadiene

Abstract

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