TY - JOUR
T1 - Mechanistic insights into thermal stability improvement of exo -tetrahydrodicyclopentadiene by a new hydrogen donor
T2 - 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline
AU - Park, Sun Hee
AU - Park, Yumi
AU - Han, Jeong Sik
AU - Jeong, Byung Hun
AU - Han, Hogyu
AU - Kim, Sung Hyun
N1 - Publisher Copyright:
© 2014 American Chemical Society.
PY - 2015/1/15
Y1 - 2015/1/15
N2 - We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.
AB - We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.
UR - http://www.scopus.com/inward/record.url?scp=84921422831&partnerID=8YFLogxK
U2 - 10.1021/ef5016445
DO - 10.1021/ef5016445
M3 - Article
AN - SCOPUS:84921422831
SN - 0887-0624
VL - 29
SP - 16
EP - 20
JO - Energy and Fuels
JF - Energy and Fuels
IS - 1
ER -