Mechanistic insights into thermal stability improvement of exo -tetrahydrodicyclopentadiene by a new hydrogen donor: 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline

Sun Hee Park; Yumi Park; Jeong Sik Han; Byung Hun Jeong; Hogyu Han; Sung Hyun Kim

doi:10.1021/ef5016445

Mechanistic insights into thermal stability improvement of exo -tetrahydrodicyclopentadiene by a new hydrogen donor: 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline

Sun Hee Park
, Yumi Park
, Jeong Sik Han
, Byung Hun Jeong
, Hogyu Han
, Sung Hyun Kim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C₁₀H₁₆) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.

Original language	English
Pages (from-to)	16-20
Number of pages	5
Journal	Energy and Fuels
Volume	29
Issue number	1
DOIs	https://doi.org/10.1021/ef5016445
Publication status	Published - 2015 Jan 15

Bibliographical note

Publisher Copyright:
© 2014 American Chemical Society.

ASJC Scopus subject areas

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology

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10.1021/ef5016445

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title = "Mechanistic insights into thermal stability improvement of exo -tetrahydrodicyclopentadiene by a new hydrogen donor: 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline",

abstract = "We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.",

author = "Park, \{Sun Hee\} and Yumi Park and Han, \{Jeong Sik\} and Jeong, \{Byung Hun\} and Hogyu Han and Kim, \{Sung Hyun\}",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

year = "2015",

month = jan,

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doi = "10.1021/ef5016445",

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T2 - 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline

AU - Park, Sun Hee

AU - Park, Yumi

AU - Han, Jeong Sik

AU - Jeong, Byung Hun

AU - Han, Hogyu

AU - Kim, Sung Hyun

PY - 2015/1/15

Y1 - 2015/1/15

N2 - We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.

AB - We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.

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U2 - 10.1021/ef5016445

DO - 10.1021/ef5016445

M3 - Article

AN - SCOPUS:84921422831

SN - 0887-0624

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JO - Energy and Fuels

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IS - 1

ER -

Mechanistic insights into thermal stability improvement of exo -tetrahydrodicyclopentadiene by a new hydrogen donor: 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline

Abstract

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ASJC Scopus subject areas

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