Metal effects on the thermal decomposition of exo - tetrahydrodicyclopentadiene

Sun Hee Park; Joongyeon Kim; Jeong Hwan Chun; Wonkeun Chung; Sang Gon Kim; Chang Hun Lee; Byung Hee Chun; Jeong Sik Han; Byung Hun Jeong; Hogyu Han; Sung Hyun Kim

doi:10.1021/ie302573n

Metal effects on the thermal decomposition of exo - tetrahydrodicyclopentadiene

Sun Hee Park, Joongyeon Kim, Jeong Hwan Chun, Wonkeun Chung, Sang Gon Kim, Chang Hun Lee, Byung Hee Chun, Jeong Sik Han, Byung Hun Jeong, Hogyu Han, Sung Hyun Kim

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

We investigated the thermal decomposition of exo- tetrahydrodicyclopentadiene (exo-THDCP, C₁₀H₁₆) in the absence and presence of various metals, Ti, SS316, SS304, Fe, Ni, and Cu. It was found that conversion of exo-THDCP was faster in the presence of metals as compared to in their absence. The order of the metal effects on the increase in the conversion of exo-THDCP was Ti < SS316 < SS304 < Fe < Ni < Cu. The metal-induced increase in the conversion of exo-THDCP was higher at the higher temperature. In addition, the metal-induced increases in the rates of C_5-9, C_15-, and C_sd product formations were higher than those of ≤C₄ and C_10-14. The composition and crystallinity of metal surfaces were found to be associated with the distinct metal effects on the thermal decomposition of exo-THDCP.

Original language	English
Pages (from-to)	4395-4400
Number of pages	6
Journal	Industrial and Engineering Chemistry Research
Volume	52
Issue number	12
DOIs	https://doi.org/10.1021/ie302573n
Publication status	Published - 2013 Mar 27

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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title = "Metal effects on the thermal decomposition of exo - tetrahydrodicyclopentadiene",

abstract = "We investigated the thermal decomposition of exo- tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of various metals, Ti, SS316, SS304, Fe, Ni, and Cu. It was found that conversion of exo-THDCP was faster in the presence of metals as compared to in their absence. The order of the metal effects on the increase in the conversion of exo-THDCP was Ti < SS316 < SS304 < Fe < Ni < Cu. The metal-induced increase in the conversion of exo-THDCP was higher at the higher temperature. In addition, the metal-induced increases in the rates of C5-9, C15-, and Csd product formations were higher than those of ≤C4 and C10-14. The composition and crystallinity of metal surfaces were found to be associated with the distinct metal effects on the thermal decomposition of exo-THDCP.",

author = "Park, {Sun Hee} and Joongyeon Kim and Chun, {Jeong Hwan} and Wonkeun Chung and Kim, {Sang Gon} and Lee, {Chang Hun} and Chun, {Byung Hee} and Han, {Jeong Sik} and Jeong, {Byung Hun} and Hogyu Han and Kim, {Sung Hyun}",

year = "2013",

month = mar,

day = "27",

doi = "10.1021/ie302573n",

language = "English",

volume = "52",

pages = "4395--4400",

journal = "Industrial and Engineering Chemistry Research",

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TY - JOUR

T1 - Metal effects on the thermal decomposition of exo - tetrahydrodicyclopentadiene

AU - Park, Sun Hee

AU - Kim, Joongyeon

AU - Chun, Jeong Hwan

AU - Chung, Wonkeun

AU - Kim, Sang Gon

AU - Lee, Chang Hun

AU - Chun, Byung Hee

AU - Han, Jeong Sik

AU - Jeong, Byung Hun

AU - Han, Hogyu

AU - Kim, Sung Hyun

PY - 2013/3/27

Y1 - 2013/3/27

N2 - We investigated the thermal decomposition of exo- tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of various metals, Ti, SS316, SS304, Fe, Ni, and Cu. It was found that conversion of exo-THDCP was faster in the presence of metals as compared to in their absence. The order of the metal effects on the increase in the conversion of exo-THDCP was Ti < SS316 < SS304 < Fe < Ni < Cu. The metal-induced increase in the conversion of exo-THDCP was higher at the higher temperature. In addition, the metal-induced increases in the rates of C5-9, C15-, and Csd product formations were higher than those of ≤C4 and C10-14. The composition and crystallinity of metal surfaces were found to be associated with the distinct metal effects on the thermal decomposition of exo-THDCP.

AB - We investigated the thermal decomposition of exo- tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of various metals, Ti, SS316, SS304, Fe, Ni, and Cu. It was found that conversion of exo-THDCP was faster in the presence of metals as compared to in their absence. The order of the metal effects on the increase in the conversion of exo-THDCP was Ti < SS316 < SS304 < Fe < Ni < Cu. The metal-induced increase in the conversion of exo-THDCP was higher at the higher temperature. In addition, the metal-induced increases in the rates of C5-9, C15-, and Csd product formations were higher than those of ≤C4 and C10-14. The composition and crystallinity of metal surfaces were found to be associated with the distinct metal effects on the thermal decomposition of exo-THDCP.

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U2 - 10.1021/ie302573n

DO - 10.1021/ie302573n

M3 - Article

AN - SCOPUS:84875747577

SN - 0888-5885

VL - 52

SP - 4395

EP - 4400

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 12

ER -

Metal effects on the thermal decomposition of exo - tetrahydrodicyclopentadiene

Abstract

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