Metal-Organic Framework Adsorbent for Practical Capture of Trace Carbon Dioxide

Jinkyoung Park; Jeoung Ryul Park; Jong Hyeak Choe; Saemi Kim; Minjung Kang; Dong Won Kang; Jee Yeon Kim; Yong Won Jeong; Chang Seop Hong

doi:10.1021/acsami.0c16224

Metal-Organic Framework Adsorbent for Practical Capture of Trace Carbon Dioxide

Jinkyoung Park, Jeoung Ryul Park, Jong Hyeak Choe, Saemi Kim, Minjung Kang, Dong Won Kang, Jee Yeon Kim, Yong Won Jeong, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Control of indoor CO2 concentration to a safe level is important to human health. Metal-organic-framework-based adsorbents show superior adsorption performance at moderate CO2 concentration compared to other solid adsorbents but suffer from low capacities and high regeneration temperature at indoor CO2 concentrations and poor humidity stability. Herein, we report epn-grafted Mg2(dobpdc) (epn = 1-ethylpropane-1,3-diamine) showing a CO2 capacity of 12.2 wt % at an acceptable concentration of 1000 ppm and a practically low desorption temperature of 70 °C, which surpasses the performance of conventional solid adsorbents under the given conditions. After poly(dimethylsiloxane) coating, this material reveals a significant adsorption amount (∼10 wt %) in humid conditions (up to 98% relative humidity) with structural durability.

Original language	English
Pages (from-to)	50534-50540
Number of pages	7
Journal	ACS Applied Materials and Interfaces
Volume	12
Issue number	45
DOIs	https://doi.org/10.1021/acsami.0c16224
Publication status	Published - 2020 Nov 11

Keywords

PDMS coating
amine functionalization
indoor air capture
metal-organic framework
ultra-microproliferation

ASJC Scopus subject areas

Materials Science(all)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acsami.0c16224

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title = "Metal-Organic Framework Adsorbent for Practical Capture of Trace Carbon Dioxide",

abstract = "Control of indoor CO2 concentration to a safe level is important to human health. Metal-organic-framework-based adsorbents show superior adsorption performance at moderate CO2 concentration compared to other solid adsorbents but suffer from low capacities and high regeneration temperature at indoor CO2 concentrations and poor humidity stability. Herein, we report epn-grafted Mg2(dobpdc) (epn = 1-ethylpropane-1,3-diamine) showing a CO2 capacity of 12.2 wt % at an acceptable concentration of 1000 ppm and a practically low desorption temperature of 70 °C, which surpasses the performance of conventional solid adsorbents under the given conditions. After poly(dimethylsiloxane) coating, this material reveals a significant adsorption amount (∼10 wt %) in humid conditions (up to 98% relative humidity) with structural durability.",

keywords = "PDMS coating, amine functionalization, indoor air capture, metal-organic framework, ultra-microproliferation",

author = "Jinkyoung Park and Park, {Jeoung Ryul} and Choe, {Jong Hyeak} and Saemi Kim and Minjung Kang and Kang, {Dong Won} and Kim, {Jee Yeon} and Jeong, {Yong Won} and Hong, {Chang Seop}",

note = "Funding Information: This work was supported by Samsung Research, Samsung Electronics Co., Ltd., the Basic Science Research Program (NRF-2018R1A2A1A05079297), the Priority Research Centers Program (NRF-2019R1A6A1A11044070), and PAL. Publisher Copyright: {\textcopyright} 2020 American Chemical Society. All rights reserved.",

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doi = "10.1021/acsami.0c16224",

language = "English",

volume = "12",

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AU - Park, Jinkyoung

AU - Park, Jeoung Ryul

AU - Choe, Jong Hyeak

AU - Kim, Saemi

AU - Kang, Minjung

AU - Kang, Dong Won

AU - Kim, Jee Yeon

AU - Jeong, Yong Won

AU - Hong, Chang Seop

N1 - Funding Information: This work was supported by Samsung Research, Samsung Electronics Co., Ltd., the Basic Science Research Program (NRF-2018R1A2A1A05079297), the Priority Research Centers Program (NRF-2019R1A6A1A11044070), and PAL. Publisher Copyright: © 2020 American Chemical Society. All rights reserved.

PY - 2020/11/11

Y1 - 2020/11/11

N2 - Control of indoor CO2 concentration to a safe level is important to human health. Metal-organic-framework-based adsorbents show superior adsorption performance at moderate CO2 concentration compared to other solid adsorbents but suffer from low capacities and high regeneration temperature at indoor CO2 concentrations and poor humidity stability. Herein, we report epn-grafted Mg2(dobpdc) (epn = 1-ethylpropane-1,3-diamine) showing a CO2 capacity of 12.2 wt % at an acceptable concentration of 1000 ppm and a practically low desorption temperature of 70 °C, which surpasses the performance of conventional solid adsorbents under the given conditions. After poly(dimethylsiloxane) coating, this material reveals a significant adsorption amount (∼10 wt %) in humid conditions (up to 98% relative humidity) with structural durability.

AB - Control of indoor CO2 concentration to a safe level is important to human health. Metal-organic-framework-based adsorbents show superior adsorption performance at moderate CO2 concentration compared to other solid adsorbents but suffer from low capacities and high regeneration temperature at indoor CO2 concentrations and poor humidity stability. Herein, we report epn-grafted Mg2(dobpdc) (epn = 1-ethylpropane-1,3-diamine) showing a CO2 capacity of 12.2 wt % at an acceptable concentration of 1000 ppm and a practically low desorption temperature of 70 °C, which surpasses the performance of conventional solid adsorbents under the given conditions. After poly(dimethylsiloxane) coating, this material reveals a significant adsorption amount (∼10 wt %) in humid conditions (up to 98% relative humidity) with structural durability.

KW - PDMS coating

KW - amine functionalization

KW - indoor air capture

KW - metal-organic framework

KW - ultra-microproliferation

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ER -

Metal-Organic Framework Adsorbent for Practical Capture of Trace Carbon Dioxide

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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