TY - JOUR
T1 - Metal-organic-framework-derived 3D crumpled carbon nanosheets with self-assembled CoxSy nanocatalysts as an interlayer for lithium-sulfur batteries
AU - Seo, Seung Deok
AU - Choi, Changhoon
AU - Park, Dongjoo
AU - Lee, Dong Yeop
AU - Park, Sangbaek
AU - Kim, Dong Wan
N1 - Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science and ICT (2019R1A2B5B02070203), by Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by Ministry of Science and ICT (2018M3D1A1058744). This work was supported by a Korea University Grant.
Publisher Copyright:
© 2020 Elsevier B.V.
PY - 2020/11/15
Y1 - 2020/11/15
N2 - Two-dimensional (2D) nanosheets are promising interlayers for enhancing the electrical conductivity and hindering the lithium polysulfide (LPS) shuttling in lithium–sulfur batteries (LSB). However, their dense 2D nature limits the electrolyte infusion and lithium ion transport, thereby decreasing the rate performance. Herein, we demonstrate that three-dimensional (3D) crumpled carbon nanosheets (CCNSs) decorated with a few nanometers of cobalt heterostructures (CoxSy) that are based on a 2D zeolitic imidazolate framework can improve both the LPS adsorption as well as the ion conduction of LSB interlayer. The method is simple and scalable; the 3D composites are fabricated by post-annealing of 2D metal organic frameworks, which are synthesized by a solution process at room temperature without surfactant. Interestingly, the assembly and polarity of cobalt heterostructures can be further manipulated by the annealing condition; this provides a scientific evidence for the nanostructural and compositional combination of polar compounds. Consequently, CoS/Co9S8@CCNS exhibits the best performance with a discharge capacity of 911 mA h g−1 at 0.2C after 100 cycles (150% more than commercial sulfur cell) and the long-term cyclability of 600 mA h g−1 at 1C after 500 cycles. This is attributed to efficient charge transfer as well as effective LPS adsorption and effective catalytic conversion; further, this is achieved by the synergetic effects of well-distributed polar compounds comprising few nanometers in size and optimal polarity on a highly conductive N-doped carbon nanosheet.
AB - Two-dimensional (2D) nanosheets are promising interlayers for enhancing the electrical conductivity and hindering the lithium polysulfide (LPS) shuttling in lithium–sulfur batteries (LSB). However, their dense 2D nature limits the electrolyte infusion and lithium ion transport, thereby decreasing the rate performance. Herein, we demonstrate that three-dimensional (3D) crumpled carbon nanosheets (CCNSs) decorated with a few nanometers of cobalt heterostructures (CoxSy) that are based on a 2D zeolitic imidazolate framework can improve both the LPS adsorption as well as the ion conduction of LSB interlayer. The method is simple and scalable; the 3D composites are fabricated by post-annealing of 2D metal organic frameworks, which are synthesized by a solution process at room temperature without surfactant. Interestingly, the assembly and polarity of cobalt heterostructures can be further manipulated by the annealing condition; this provides a scientific evidence for the nanostructural and compositional combination of polar compounds. Consequently, CoS/Co9S8@CCNS exhibits the best performance with a discharge capacity of 911 mA h g−1 at 0.2C after 100 cycles (150% more than commercial sulfur cell) and the long-term cyclability of 600 mA h g−1 at 1C after 500 cycles. This is attributed to efficient charge transfer as well as effective LPS adsorption and effective catalytic conversion; further, this is achieved by the synergetic effects of well-distributed polar compounds comprising few nanometers in size and optimal polarity on a highly conductive N-doped carbon nanosheet.
KW - 2D-ZIF nanosheets
KW - Carbon nanosheets
KW - Cobalt sulfide catalyst
KW - Lithium polysulfide adsorption
KW - Lithium-sulfur batteries
UR - http://www.scopus.com/inward/record.url?scp=85086729667&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2020.125959
DO - 10.1016/j.cej.2020.125959
M3 - Article
AN - SCOPUS:85086729667
SN - 1385-8947
VL - 400
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
M1 - 125959
ER -