Abstract
Isostructural lanthanide-organic frameworks were prepared by a solvothermal reaction of the corresponding metal ions and the phosphine-oxide-based tricarboxylate ligand. The gravimetric gas uptake was unexpectedly increased when going from Nd3+ to Gd3+, which is associated with the enhanced surface areas and electrostatic interactions between exposed metal ions and gas molecules with quadrupole moments.
Original language | English |
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Pages (from-to) | 4723-4725 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 49 |
Issue number | 11 |
DOIs | |
Publication status | Published - 2010 Jun 7 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry