Microstructure and Magnetic Properties of NdFeB Sintered Magnets Diffusion-Treated with Cu/Al Mixed Dyco Alloy-Powder

M. W. Lee, K. H. Bae, S. R. Lee, H. J. Kim, T. S. Jang

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)


We investigated the microstructural and magnetic property changes of DyCo, Cu + DyCo, and Al + DyCo diffusion-treated NdFeB sintered magnets. The coercivity of all diffusion treated magnet was increased at 880C of 1st post annealing(PA), by 6.1 kOe in Cu and 7.0 kOe in Al mixed DyCo coated magnets, whereas this increment was found to be relatively low (3.9 kOe) in the magnet coated with DyCo only. The diffusivity and diffusion depth of Dy were increased in those magnets which were treated with Cu or Al mixed DyCo, mainly due to comparatively easy diffusion path provided by Cu and Al because of their solubility with Ndrich grain boundary phase. The formation of Cu/Al-rich grain boundary phase might have enhanced the diffusivity of Dy-atoms. Moreover, relatively a large number of Dy atoms reached into the magnet and mostly segregated at the interface of Nd2Fe14B and grain boundary phases covering Nd2Fe14B grains so that the core-shell type structures were developed. The formation of highly anisotropic (Nd, Dy)2Fe14B phase layer, which acted as the shell in the core-shell type structure so as to prevent the reverse domain movement, was the cause of enhancing the coercivity of diffusion treated NdFeB magnets. Segregation of cobalt in Nd-rich TJP followed by the formation of Co-rich phase was beneficial for the coercivity enhancement, resulting in the stabilization of the metastable c-Nd2O3 phase.

Original languageEnglish
Pages (from-to)1263-1266
Number of pages4
JournalArchives of Metallurgy and Materials
Issue number2
Publication statusPublished - 2017 Jun 1


  • DyCo alloy-powder diffusion
  • Nd-Fe-B sintered magnet
  • grain boundary diffusion process
  • low melting-point elements

ASJC Scopus subject areas

  • Metals and Alloys


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