MOF-74 type variants for CO2capture

Jong Hyeak Choe; Hyojin Kim; Chang Seop Hong

doi:10.1039/d1qm00205h

MOF-74 type variants for CO₂capture

Jong Hyeak Choe, Hyojin Kim, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Review article › peer-review

76 Citations (Scopus)

Abstract

Carbon capture and storage (CCS) is aimed at disposing the carbon dioxide (CO2) generated by power plants. As next-generation adsorbents, metal-organic framework (MOF) adsorbents with high surface area, tunable pore size, and low heat capacity are in the spotlight for CCS applications. Among the known MOFs, MOF-74 type analogs exhibit high CO2 adsorption performance due to the open metal sites in the hexagonal channels aligned along the c-axis. Extensive studies on such adsorbents have been carried out to control CO2 adsorption and enable selective adsorption even under wet conditions. From this perspective, this review addresses not only the CO2 adsorption properties of the MOF-74 type structures, but also their enhanced CO2 capacity through modifications of organic linkers and open metal sites of the frameworks.

Original language	English
Pages (from-to)	5172-5185
Number of pages	14
Journal	Materials Chemistry Frontiers
Volume	5
Issue number	14
DOIs	https://doi.org/10.1039/d1qm00205h
Publication status	Published - 2021 Jul 21

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (NRF-2018R1A2A1A05079297) and the Priority Research Centers Program (NRF-2019R1A6A1A11044070).

Publisher Copyright:
© the Partner Organisations.

ASJC Scopus subject areas

General Materials Science
Materials Chemistry

Access to Document

10.1039/d1qm00205h

Cite this

@article{16d46da1a06045b289fee1c0125c09c9,

title = "MOF-74 type variants for CO2capture",

abstract = "Carbon capture and storage (CCS) is aimed at disposing the carbon dioxide (CO2) generated by power plants. As next-generation adsorbents, metal-organic framework (MOF) adsorbents with high surface area, tunable pore size, and low heat capacity are in the spotlight for CCS applications. Among the known MOFs, MOF-74 type analogs exhibit high CO2 adsorption performance due to the open metal sites in the hexagonal channels aligned along the c-axis. Extensive studies on such adsorbents have been carried out to control CO2 adsorption and enable selective adsorption even under wet conditions. From this perspective, this review addresses not only the CO2 adsorption properties of the MOF-74 type structures, but also their enhanced CO2 capacity through modifications of organic linkers and open metal sites of the frameworks.",

author = "Choe, {Jong Hyeak} and Hyojin Kim and Hong, {Chang Seop}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (NRF-2018R1A2A1A05079297) and the Priority Research Centers Program (NRF-2019R1A6A1A11044070). Publisher Copyright: {\textcopyright} the Partner Organisations.",

year = "2021",

month = jul,

day = "21",

doi = "10.1039/d1qm00205h",

language = "English",

volume = "5",

pages = "5172--5185",

journal = "Materials Chemistry Frontiers",

issn = "2052-1537",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - MOF-74 type variants for CO2capture

AU - Choe, Jong Hyeak

AU - Kim, Hyojin

AU - Hong, Chang Seop

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (NRF-2018R1A2A1A05079297) and the Priority Research Centers Program (NRF-2019R1A6A1A11044070). Publisher Copyright: © the Partner Organisations.

PY - 2021/7/21

Y1 - 2021/7/21

N2 - Carbon capture and storage (CCS) is aimed at disposing the carbon dioxide (CO2) generated by power plants. As next-generation adsorbents, metal-organic framework (MOF) adsorbents with high surface area, tunable pore size, and low heat capacity are in the spotlight for CCS applications. Among the known MOFs, MOF-74 type analogs exhibit high CO2 adsorption performance due to the open metal sites in the hexagonal channels aligned along the c-axis. Extensive studies on such adsorbents have been carried out to control CO2 adsorption and enable selective adsorption even under wet conditions. From this perspective, this review addresses not only the CO2 adsorption properties of the MOF-74 type structures, but also their enhanced CO2 capacity through modifications of organic linkers and open metal sites of the frameworks.

AB - Carbon capture and storage (CCS) is aimed at disposing the carbon dioxide (CO2) generated by power plants. As next-generation adsorbents, metal-organic framework (MOF) adsorbents with high surface area, tunable pore size, and low heat capacity are in the spotlight for CCS applications. Among the known MOFs, MOF-74 type analogs exhibit high CO2 adsorption performance due to the open metal sites in the hexagonal channels aligned along the c-axis. Extensive studies on such adsorbents have been carried out to control CO2 adsorption and enable selective adsorption even under wet conditions. From this perspective, this review addresses not only the CO2 adsorption properties of the MOF-74 type structures, but also their enhanced CO2 capacity through modifications of organic linkers and open metal sites of the frameworks.

UR - http://www.scopus.com/inward/record.url?scp=85110201798&partnerID=8YFLogxK

U2 - 10.1039/d1qm00205h

DO - 10.1039/d1qm00205h

M3 - Review article

AN - SCOPUS:85110201798

SN - 2052-1537

VL - 5

SP - 5172

EP - 5185

JO - Materials Chemistry Frontiers

JF - Materials Chemistry Frontiers

IS - 14

ER -