Non-isothermal pyrolysis of waste automobile lubricating oil in a stirred batch reactor

Seung Soo Kim; Byung Hee Chun; Sung Hyun Kim

doi:10.1016/S1385-8947(02)00262-0

Non-isothermal pyrolysis of waste automobile lubricating oil in a stirred batch reactor

Seung Soo Kim^*, Byung Hee Chun, Sung Hyun Kim

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Kinetic tests on pyrolysis of waste automobile lubricating were carried out with a thermogravimetric analysis (TGA) technique at heating rates of 0.5, 1.0, and 2.0°C min^-1 in a stirred batch reactor. The main region of decomposition of waste automobile lubricating oil was between 400 and 460 °C at each heating rate. The corresponding kinetic parameters including activation energy were determined by the degree of conversions. The ranges of activation energies were from 281.78 to 447.66 kJ mol^-1 at conversion in the range of 0.11-0.96 and the reaction order was 1.35. The effects of heating rate on the product distribution have been studied. The distribution of the liquid products shifted slightly to smaller carbon numbers as the heating rate decreased.

Original language	English
Pages (from-to)	225-231
Number of pages	7
Journal	Chemical Engineering Journal
Volume	93
Issue number	3
DOIs	https://doi.org/10.1016/S1385-8947(02)00262-0
Publication status	Published - 2003 Jul 1

Keywords

Carbon number distribution
Pyrolysis
Stirred batch reactor
TGA
Waste automobile lubricating oil

ASJC Scopus subject areas

General Chemistry
Environmental Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

Access to Document

10.1016/S1385-8947(02)00262-0

Cite this

@article{293b64bd41294b4b91165a54128199ab,

title = "Non-isothermal pyrolysis of waste automobile lubricating oil in a stirred batch reactor",

abstract = "Kinetic tests on pyrolysis of waste automobile lubricating were carried out with a thermogravimetric analysis (TGA) technique at heating rates of 0.5, 1.0, and 2.0°C min-1 in a stirred batch reactor. The main region of decomposition of waste automobile lubricating oil was between 400 and 460 °C at each heating rate. The corresponding kinetic parameters including activation energy were determined by the degree of conversions. The ranges of activation energies were from 281.78 to 447.66 kJ mol-1 at conversion in the range of 0.11-0.96 and the reaction order was 1.35. The effects of heating rate on the product distribution have been studied. The distribution of the liquid products shifted slightly to smaller carbon numbers as the heating rate decreased.",

keywords = "Carbon number distribution, Pyrolysis, Stirred batch reactor, TGA, Waste automobile lubricating oil",

author = "Kim, \{Seung Soo\} and Chun, \{Byung Hee\} and Kim, \{Sung Hyun\}",

year = "2003",

month = jul,

day = "1",

doi = "10.1016/S1385-8947(02)00262-0",

language = "English",

volume = "93",

pages = "225--231",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Non-isothermal pyrolysis of waste automobile lubricating oil in a stirred batch reactor

AU - Kim, Seung Soo

AU - Chun, Byung Hee

AU - Kim, Sung Hyun

PY - 2003/7/1

Y1 - 2003/7/1

N2 - Kinetic tests on pyrolysis of waste automobile lubricating were carried out with a thermogravimetric analysis (TGA) technique at heating rates of 0.5, 1.0, and 2.0°C min-1 in a stirred batch reactor. The main region of decomposition of waste automobile lubricating oil was between 400 and 460 °C at each heating rate. The corresponding kinetic parameters including activation energy were determined by the degree of conversions. The ranges of activation energies were from 281.78 to 447.66 kJ mol-1 at conversion in the range of 0.11-0.96 and the reaction order was 1.35. The effects of heating rate on the product distribution have been studied. The distribution of the liquid products shifted slightly to smaller carbon numbers as the heating rate decreased.

AB - Kinetic tests on pyrolysis of waste automobile lubricating were carried out with a thermogravimetric analysis (TGA) technique at heating rates of 0.5, 1.0, and 2.0°C min-1 in a stirred batch reactor. The main region of decomposition of waste automobile lubricating oil was between 400 and 460 °C at each heating rate. The corresponding kinetic parameters including activation energy were determined by the degree of conversions. The ranges of activation energies were from 281.78 to 447.66 kJ mol-1 at conversion in the range of 0.11-0.96 and the reaction order was 1.35. The effects of heating rate on the product distribution have been studied. The distribution of the liquid products shifted slightly to smaller carbon numbers as the heating rate decreased.

KW - Carbon number distribution

KW - Pyrolysis

KW - Stirred batch reactor

KW - TGA

KW - Waste automobile lubricating oil

UR - https://www.scopus.com/pages/publications/0038318826

UR - https://www.scopus.com/inward/citedby.url?scp=0038318826&partnerID=8YFLogxK

U2 - 10.1016/S1385-8947(02)00262-0

DO - 10.1016/S1385-8947(02)00262-0

M3 - Article

AN - SCOPUS:0038318826

SN - 1385-8947

VL - 93

SP - 225

EP - 231

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

IS - 3

ER -

Non-isothermal pyrolysis of waste automobile lubricating oil in a stirred batch reactor

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this