Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework

Bo Keun Park; M. Arzu Miah; Gaehang Lee; Youn Jaung Cho; Kwangyeol Lee; Sangwoo Park; Moon Gun Choi; Joon T. Park

doi:10.1002/anie.200353290

Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework

Bo Keun Park, M. Arzu Miah, Gaehang Lee, Youn Jaung Cho, Kwangyeol Lee, Sangwoo Park, Moon Gun Choi, Joon T. Park

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A mono- to di- and triphosphane transformation occurs on treatment of [Ir₄(CO)₉(PPh₃)₃] (1) with C ₆₀ to successively afford 2 and 3. The noninnocent, multifunctional C₆₀ ligand plays a crucial role in transforming three PPh₃ ligands into a μ₃-PPh₂(o-C₆H₄) P(o-C₆H₄) PPh(η¹-o-C₆H ₄) triphosphane ligand by a series of ortho-phosphanation and ortho-metalation processes on the Ir₄ cluster framework.

Original language	English
Pages (from-to)	1712-1714
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	13
DOIs	https://doi.org/10.1002/anie.200353290
Publication status	Published - 2004 Mar 19

Keywords

Cluster compounds
Fullerenes
Iridium
P ligands
Phosphanation

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200353290

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title = "Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework",

abstract = "A mono- to di- and triphosphane transformation occurs on treatment of [Ir4(CO)9(PPh3)3] (1) with C 60 to successively afford 2 and 3. The noninnocent, multifunctional C60 ligand plays a crucial role in transforming three PPh3 ligands into a μ3-PPh2(o-C6H4) P(o-C6H4) PPh(η1-o-C6H 4) triphosphane ligand by a series of ortho-phosphanation and ortho-metalation processes on the Ir4 cluster framework.",

keywords = "Cluster compounds, Fullerenes, Iridium, P ligands, Phosphanation",

author = "Park, {Bo Keun} and Miah, {M. Arzu} and Gaehang Lee and Cho, {Youn Jaung} and Kwangyeol Lee and Sangwoo Park and Choi, {Moon Gun} and Park, {Joon T.}",

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AU - Park, Bo Keun

AU - Miah, M. Arzu

AU - Lee, Gaehang

AU - Cho, Youn Jaung

AU - Lee, Kwangyeol

AU - Park, Sangwoo

AU - Choi, Moon Gun

AU - Park, Joon T.

PY - 2004/3/19

Y1 - 2004/3/19

N2 - A mono- to di- and triphosphane transformation occurs on treatment of [Ir4(CO)9(PPh3)3] (1) with C 60 to successively afford 2 and 3. The noninnocent, multifunctional C60 ligand plays a crucial role in transforming three PPh3 ligands into a μ3-PPh2(o-C6H4) P(o-C6H4) PPh(η1-o-C6H 4) triphosphane ligand by a series of ortho-phosphanation and ortho-metalation processes on the Ir4 cluster framework.

AB - A mono- to di- and triphosphane transformation occurs on treatment of [Ir4(CO)9(PPh3)3] (1) with C 60 to successively afford 2 and 3. The noninnocent, multifunctional C60 ligand plays a crucial role in transforming three PPh3 ligands into a μ3-PPh2(o-C6H4) P(o-C6H4) PPh(η1-o-C6H 4) triphosphane ligand by a series of ortho-phosphanation and ortho-metalation processes on the Ir4 cluster framework.

KW - Cluster compounds

KW - Fullerenes

KW - Iridium

KW - P ligands

KW - Phosphanation

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Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework

Abstract

Keywords

ASJC Scopus subject areas

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