Abstract
The 1H nuclear spin-lattice relaxation behavior was characterized in the perovskite-type layered structure quasi-two-dimensional Heisenberg paramagnets, (CnH2n+1NH3) 2MnCl4,with different chain lengths (n = 8, 10, and 12). In contrast to the case of the short-chain compound with n = 8, the nuclear spin diffusion to the electron spin system alone is not able to fully account for the spin-lattice relaxation in the compounds with longer chain lengths. Our results are discussed in light of the nuclear magnetic relaxation by the regularly distributed dense paramagnetic ions.
| Original language | English |
|---|---|
| Pages (from-to) | 527-530 |
| Number of pages | 4 |
| Journal | Solid State Communications |
| Volume | 131 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2004 Aug 1 |
Bibliographical note
Funding Information:This work was supported by the KISTEP (National Research Laboratory and M102KS010001-02K1901-01814) and by the Brain Korea 21 Project in 2003. We thank the Korea Basic Science Institute for the NMR measurements.
Keywords
- D. Spin dynamics
- E. Nuclear resonances
ASJC Scopus subject areas
- General Chemistry
- Condensed Matter Physics
- Materials Chemistry
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