Observation of spontaneous ferroelectric polarization reversal in multiferroic Mn1-xNixW04 (x ≈ 0.16)

Young Sang Song, Jae Ho Chung, Kwang Woo Shin, Kee Hoon Kim, In Hwan Oh

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)


In this Letter, we report the effect of replacing Mn2+ ions with Ni2+on the ferroelectricity of multiferroic MnW04 single crystals. When the amount of substitution was close to 16%, the sign of ferroelectric polarization spontaneously became negative with respect to initial dc poling field at a few degrees below Tc. Neutron diffraction intensities revealed a sudden change in the underlying spiral spin ordering that occurred coincidentally with the observed sign reversal. This unusual behavior in zero magnetic fields suggests that strong competitions between the two different magnetic ions may provide an efficient route to manipulation of existing multiferroics.

Original languageEnglish
Article number252904
JournalApplied Physics Letters
Issue number25
Publication statusPublished - 2014 Jun 23

Bibliographical note

Funding Information:
This work was financially supported by the National Research Foundation of Korea through the ARCNEX (NRF-2011-0031933) and the Nuclear R&D Programs (NRF- 2013M2A2A6029081). The work at SNU was supported by the Creative Research Initiative (2010-0018300).

Publisher Copyright:
© 2014 AIP Publishing LLC.

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)


Dive into the research topics of 'Observation of spontaneous ferroelectric polarization reversal in multiferroic Mn1-xNixW04 (x ≈ 0.16)'. Together they form a unique fingerprint.

Cite this