Cyanide-bridged MVMnIII (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)8]3- precursors and MnIII Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.
|Number of pages||3|
|Publication status||Published - 2009 Jul 6|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry