One-pot synthesis of Fe3O4/Fe/MWCNT nanocomposites via electrical wire pulse for Li ion battery electrodes

Duk Hee Lee; Seung Deok Seo; Gwang Hee Lee; Hyun Seon Hong; Dong Wan Kim

doi:10.1016/j.jallcom.2014.04.023

One-pot synthesis of Fe₃O₄/Fe/MWCNT nanocomposites via electrical wire pulse for Li ion battery electrodes

Duk Hee Lee, Seung Deok Seo, Gwang Hee Lee, Hyun Seon Hong, Dong Wan Kim

School of Civil, Environmental and Architectural Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Nanocomposites containing Fe₃O₄/Fe/multiwalled carbon nanotubes (MWCNT) were prepared via an electrical wire pulse process (a top-down approach) using Fe wire and dispersed, functionalized MWCNT in deionized water (DIW) at room temperature. The structural and electrochemical characteristics of the resulting nanocomposites were investigated in detail. When used as an anode for Li ion batteries, the Fe₃O ₄/Fe/MWCNT nanocomposites exhibited greater cycle stability and rate performance than plain Fe₃O₄/Fe composites, with a capacity of 460 mA h g^-1 at a rate of 168 mA g^-1 after 50 cycles. The enhanced performance was attributed to superior electrical conductivity and buffering effect of the MWCNTs on volume changes of the anodes. This process is a promising facile method for lithium ion battery anode material synthesis.

Original language	English
Pages (from-to)	204-207
Number of pages	4
Journal	Journal of Alloys and Compounds
Volume	606
DOIs	https://doi.org/10.1016/j.jallcom.2014.04.023
Publication status	Published - 2014 Sept 5

Keywords

Electrical wire pulse process
Li ion battery
Multiwalled carbon nanotubes

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jallcom.2014.04.023

Cite this

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title = "One-pot synthesis of Fe3O4/Fe/MWCNT nanocomposites via electrical wire pulse for Li ion battery electrodes",

abstract = "Nanocomposites containing Fe3O4/Fe/multiwalled carbon nanotubes (MWCNT) were prepared via an electrical wire pulse process (a top-down approach) using Fe wire and dispersed, functionalized MWCNT in deionized water (DIW) at room temperature. The structural and electrochemical characteristics of the resulting nanocomposites were investigated in detail. When used as an anode for Li ion batteries, the Fe3O 4/Fe/MWCNT nanocomposites exhibited greater cycle stability and rate performance than plain Fe3O4/Fe composites, with a capacity of 460 mA h g-1 at a rate of 168 mA g-1 after 50 cycles. The enhanced performance was attributed to superior electrical conductivity and buffering effect of the MWCNTs on volume changes of the anodes. This process is a promising facile method for lithium ion battery anode material synthesis.",

keywords = "Electrical wire pulse process, Li ion battery, Multiwalled carbon nanotubes",

author = "Lee, {Duk Hee} and Seo, {Seung Deok} and Lee, {Gwang Hee} and Hong, {Hyun Seon} and Kim, {Dong Wan}",

note = "Funding Information: This research was supported by the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT, and Future Planning ( 2012R1A2A2A01045382 ). ",

year = "2014",

month = sep,

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doi = "10.1016/j.jallcom.2014.04.023",

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T1 - One-pot synthesis of Fe3O4/Fe/MWCNT nanocomposites via electrical wire pulse for Li ion battery electrodes

AU - Lee, Duk Hee

AU - Seo, Seung Deok

AU - Lee, Gwang Hee

AU - Hong, Hyun Seon

AU - Kim, Dong Wan

N1 - Funding Information: This research was supported by the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT, and Future Planning ( 2012R1A2A2A01045382 ).

PY - 2014/9/5

Y1 - 2014/9/5

N2 - Nanocomposites containing Fe3O4/Fe/multiwalled carbon nanotubes (MWCNT) were prepared via an electrical wire pulse process (a top-down approach) using Fe wire and dispersed, functionalized MWCNT in deionized water (DIW) at room temperature. The structural and electrochemical characteristics of the resulting nanocomposites were investigated in detail. When used as an anode for Li ion batteries, the Fe3O 4/Fe/MWCNT nanocomposites exhibited greater cycle stability and rate performance than plain Fe3O4/Fe composites, with a capacity of 460 mA h g-1 at a rate of 168 mA g-1 after 50 cycles. The enhanced performance was attributed to superior electrical conductivity and buffering effect of the MWCNTs on volume changes of the anodes. This process is a promising facile method for lithium ion battery anode material synthesis.

AB - Nanocomposites containing Fe3O4/Fe/multiwalled carbon nanotubes (MWCNT) were prepared via an electrical wire pulse process (a top-down approach) using Fe wire and dispersed, functionalized MWCNT in deionized water (DIW) at room temperature. The structural and electrochemical characteristics of the resulting nanocomposites were investigated in detail. When used as an anode for Li ion batteries, the Fe3O 4/Fe/MWCNT nanocomposites exhibited greater cycle stability and rate performance than plain Fe3O4/Fe composites, with a capacity of 460 mA h g-1 at a rate of 168 mA g-1 after 50 cycles. The enhanced performance was attributed to superior electrical conductivity and buffering effect of the MWCNTs on volume changes of the anodes. This process is a promising facile method for lithium ion battery anode material synthesis.

KW - Electrical wire pulse process

KW - Li ion battery

KW - Multiwalled carbon nanotubes

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