[Os3(CO)6(PMe3)3] (μ3-η2:η2:η2-C 60)[Re3(μ-H)3(CO)9]: A fullerene[60] coordinated to two different trinuclear clusters

Bo Keun Park; Chang Yeon Lee; Jaehoon Jung; Jung Hak Lim; Young Kyu Han; Chang Seop Hong; Joon T. Park

doi:10.1002/anie.200603882

[Os₃(CO)₆(PMe₃)₃] (μ₃-η²:η²:η²-C ₆₀)[Re₃(μ-H)₃(CO)₉]: A fullerene[60] coordinated to two different trinuclear clusters

Bo Keun Park, Chang Yeon Lee, Jaehoon Jung, Jung Hak Lim, Young Kyu Han, Chang Seop Hong, Joon T. Park

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

(Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature ¹H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.

Original language	English
Pages (from-to)	1436-1439
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	9
DOIs	https://doi.org/10.1002/anie.200603882
Publication status	Published - 2007

Keywords

Cluster compounds
Density functional calculations
Fullerenes
Osmium
Rhenium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200603882

Cite this

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abstract = "(Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature 1H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.",

keywords = "Cluster compounds, Density functional calculations, Fullerenes, Osmium, Rhenium",

author = "Park, {Bo Keun} and Lee, {Chang Yeon} and Jaehoon Jung and Lim, {Jung Hak} and Han, {Young Kyu} and Hong, {Chang Seop} and Park, {Joon T.}",

year = "2007",

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T1 - [Os3(CO)6(PMe3)3] (μ3-η2:η2:η2-C 60)[Re3(μ-H)3(CO)9]

T2 - A fullerene[60] coordinated to two different trinuclear clusters

AU - Park, Bo Keun

AU - Lee, Chang Yeon

AU - Jung, Jaehoon

AU - Lim, Jung Hak

AU - Han, Young Kyu

AU - Hong, Chang Seop

AU - Park, Joon T.

PY - 2007

Y1 - 2007

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AB - (Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature 1H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.

KW - Cluster compounds

KW - Density functional calculations

KW - Fullerenes

KW - Osmium

KW - Rhenium

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DO - 10.1002/anie.200603882

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AN - SCOPUS:34247859313

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