Palladium catalysts for dehydrogenation of ammonia borane with preferential b-h activation

Sung Kwan Kim; Won Sik Han; Tae Jin Kim; Tae Young Kim; Suk Woo Nam; Mariusz Mitoraj; Lukasz Piekoś; Artur Michalak; Son Jong Hwang; Sang Ook Kang

doi:10.1021/ja101685u

Palladium catalysts for dehydrogenation of ammonia borane with preferential b-h activation

Sung Kwan Kim, Won Sik Han, Tae Jin Kim, Tae Young Kim, Suk Woo Nam, Mariusz Mitoraj, Lukasz Piekoś, Artur Michalak, Son Jong Hwang, Sang Ook Kang

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176 Citations (Scopus)

Abstract

Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H₂ in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.

Original language	English
Pages (from-to)	9954-9955
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	29
DOIs	https://doi.org/10.1021/ja101685u
Publication status	Published - 2010 Jul 28

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja101685u

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title = "Palladium catalysts for dehydrogenation of ammonia borane with preferential b-h activation",

abstract = "Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.",

author = "Kim, {Sung Kwan} and Han, {Won Sik} and Kim, {Tae Jin} and Kim, {Tae Young} and Nam, {Suk Woo} and Mariusz Mitoraj and Lukasz Pieko{\'s} and Artur Michalak and Hwang, {Son Jong} and Kang, {Sang Ook}",

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doi = "10.1021/ja101685u",

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T1 - Palladium catalysts for dehydrogenation of ammonia borane with preferential b-h activation

AU - Kim, Sung Kwan

AU - Han, Won Sik

AU - Kim, Tae Jin

AU - Kim, Tae Young

AU - Nam, Suk Woo

AU - Mitoraj, Mariusz

AU - Piekoś, Lukasz

AU - Michalak, Artur

AU - Hwang, Son Jong

AU - Kang, Sang Ook

PY - 2010/7/28

Y1 - 2010/7/28

N2 - Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.

AB - Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.

UR - http://www.scopus.com/inward/record.url?scp=77955832702&partnerID=8YFLogxK

U2 - 10.1021/ja101685u

DO - 10.1021/ja101685u

M3 - Article

C2 - 20597488

AN - SCOPUS:77955832702

SN - 0002-7863

VL - 132

SP - 9954

EP - 9955

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 29

ER -

Palladium catalysts for dehydrogenation of ammonia borane with preferential b-h activation

Abstract

ASJC Scopus subject areas

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