Photochromic behavior of new bifunctional copolymer containing spiropyran and chalcone moiety in the side chain

Jae Hong Kim; Si Young Ban; Shen Kaihua; Dong Hoon Choi

doi:10.1016/S0143-7208(03)00052-4

Photochromic behavior of new bifunctional copolymer containing spiropyran and chalcone moiety in the side chain

Jae Hong Kim, Si Young Ban, Shen Kaihua, Dong Hoon Choi

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

We synthesized two copolymers bearing photochromic spiropyran dye in the side chain for studying the dynamic properties of their photochromism. The dynamic processes of colorization and decolorization under an excitation light were investigated using the two copolymers. One of the copolymers contains methylmethacrylate (MMA) and methacrylate-spiropyran (MA-spiropyran). The other one contains methacrylate-spiropyran (MA-spiropyran) and methacrylate- chalcone (MA-chalcone) as a comonomer. Investigation of the photosensitivity of the newly synthesized copolymers was carried out by using UV-vis absorption spectroscopy. We observed the photodimerization and photochromic behavior under UV irradiation simultaneously. The effect of photocrosslink on the stability of photochromism was considered from this study.

Original language	English
Pages (from-to)	105-112
Number of pages	8
Journal	Dyes and Pigments
Volume	58
Issue number	2
DOIs	https://doi.org/10.1016/S0143-7208(03)00052-4
Publication status	Published - 2003 Aug
Externally published	Yes

Keywords

Chalcone
Photochromism
Photocrosslink
Spiropyran
UV irradiation

ASJC Scopus subject areas

Chemical Engineering(all)
Process Chemistry and Technology

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10.1016/S0143-7208(03)00052-4

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title = "Photochromic behavior of new bifunctional copolymer containing spiropyran and chalcone moiety in the side chain",

abstract = "We synthesized two copolymers bearing photochromic spiropyran dye in the side chain for studying the dynamic properties of their photochromism. The dynamic processes of colorization and decolorization under an excitation light were investigated using the two copolymers. One of the copolymers contains methylmethacrylate (MMA) and methacrylate-spiropyran (MA-spiropyran). The other one contains methacrylate-spiropyran (MA-spiropyran) and methacrylate- chalcone (MA-chalcone) as a comonomer. Investigation of the photosensitivity of the newly synthesized copolymers was carried out by using UV-vis absorption spectroscopy. We observed the photodimerization and photochromic behavior under UV irradiation simultaneously. The effect of photocrosslink on the stability of photochromism was considered from this study.",

keywords = "Chalcone, Photochromism, Photocrosslink, Spiropyran, UV irradiation",

author = "Kim, {Jae Hong} and Ban, {Si Young} and Shen Kaihua and Choi, {Dong Hoon}",

note = "Funding Information: This work was financially supported by the Korea Research Foundation (KRF-2001-005-D00004) and Samsung Electronic Co. Ltd. (2002). ",

year = "2003",

month = aug,

doi = "10.1016/S0143-7208(03)00052-4",

language = "English",

volume = "58",

pages = "105--112",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier BV",

number = "2",

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TY - JOUR

T1 - Photochromic behavior of new bifunctional copolymer containing spiropyran and chalcone moiety in the side chain

AU - Kim, Jae Hong

AU - Ban, Si Young

AU - Kaihua, Shen

AU - Choi, Dong Hoon

N1 - Funding Information: This work was financially supported by the Korea Research Foundation (KRF-2001-005-D00004) and Samsung Electronic Co. Ltd. (2002).

PY - 2003/8

Y1 - 2003/8

N2 - We synthesized two copolymers bearing photochromic spiropyran dye in the side chain for studying the dynamic properties of their photochromism. The dynamic processes of colorization and decolorization under an excitation light were investigated using the two copolymers. One of the copolymers contains methylmethacrylate (MMA) and methacrylate-spiropyran (MA-spiropyran). The other one contains methacrylate-spiropyran (MA-spiropyran) and methacrylate- chalcone (MA-chalcone) as a comonomer. Investigation of the photosensitivity of the newly synthesized copolymers was carried out by using UV-vis absorption spectroscopy. We observed the photodimerization and photochromic behavior under UV irradiation simultaneously. The effect of photocrosslink on the stability of photochromism was considered from this study.

AB - We synthesized two copolymers bearing photochromic spiropyran dye in the side chain for studying the dynamic properties of their photochromism. The dynamic processes of colorization and decolorization under an excitation light were investigated using the two copolymers. One of the copolymers contains methylmethacrylate (MMA) and methacrylate-spiropyran (MA-spiropyran). The other one contains methacrylate-spiropyran (MA-spiropyran) and methacrylate- chalcone (MA-chalcone) as a comonomer. Investigation of the photosensitivity of the newly synthesized copolymers was carried out by using UV-vis absorption spectroscopy. We observed the photodimerization and photochromic behavior under UV irradiation simultaneously. The effect of photocrosslink on the stability of photochromism was considered from this study.

KW - Chalcone

KW - Photochromism

KW - Photocrosslink

KW - Spiropyran

KW - UV irradiation

UR - http://www.scopus.com/inward/record.url?scp=0038544508&partnerID=8YFLogxK

U2 - 10.1016/S0143-7208(03)00052-4

DO - 10.1016/S0143-7208(03)00052-4

M3 - Article

AN - SCOPUS:0038544508

SN - 0143-7208

VL - 58

SP - 105

EP - 112

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 2

ER -

Photochromic behavior of new bifunctional copolymer containing spiropyran and chalcone moiety in the side chain

Abstract

Keywords

ASJC Scopus subject areas

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