Photoluminescence properties of lead selenide produced by selenization and a solvothermal method

Jungdong Kim; Hak Young Ahn; Seung Gi Kim; Eunsoon Oh; Byeong Kwon Ju; Won Jun Choi; So Hye Cho

doi:10.1088/0957-4484/28/1/015702

Photoluminescence properties of lead selenide produced by selenization and a solvothermal method

Jungdong Kim, Hak Young Ahn, Seung Gi Kim, Eunsoon Oh, Byeong Kwon Ju, Won Jun Choi, So Hye Cho

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We studied temperature-dependent photoluminescence (PL) spectra of lead selenide (PbSe) dendrites and cubes grown by a solvothermal method. Their PL peaks were located at ∼8 μm at 10 K with a full width at half maximum (FWHM) of 10 meV. Using the temperature-dependent FWHM values, we obtained carrier-phonon coupling coefficients for PbSe. We also demonstrated mechanochemical synthesis of polycrystalline PbS nanoparticles and their successful conversion into a PbSe layer composed of nanocrystals by a selenization process with thermal treatment. The nanocrystals were found to be formed by the orientation alignment of small grains in the process. The PL peak energies of the PbSe layers as well as the PbSe dendrites and the cubes agreed well with their absorption edges in the transmission spectra, indicating that the photoluminescence originates from the band-edge emission. The band-edge emissions hold promise for the development of potential mid-infrared light sources using PbSe fabricated by these methods.

Original language	English
Article number	015702
Journal	Nanotechnology
Volume	28
Issue number	1
DOIs	https://doi.org/10.1088/0957-4484/28/1/015702
Publication status	Published - 2017 Jan 6

Bibliographical note

Funding Information:
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2015052280), by Chungnam National University and by the Korea Institute of Science and Technology (project No. 2E26120).

Publisher Copyright:
© 2016 IOP Publishing Ltd.

Keywords

FWHM
carrier-phonon interaction
lead selenide
mid-infrared
photoluminescence
selenization

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Mechanics of Materials
Mechanical Engineering
Electrical and Electronic Engineering

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title = "Photoluminescence properties of lead selenide produced by selenization and a solvothermal method",

abstract = "We studied temperature-dependent photoluminescence (PL) spectra of lead selenide (PbSe) dendrites and cubes grown by a solvothermal method. Their PL peaks were located at ∼8 μm at 10 K with a full width at half maximum (FWHM) of 10 meV. Using the temperature-dependent FWHM values, we obtained carrier-phonon coupling coefficients for PbSe. We also demonstrated mechanochemical synthesis of polycrystalline PbS nanoparticles and their successful conversion into a PbSe layer composed of nanocrystals by a selenization process with thermal treatment. The nanocrystals were found to be formed by the orientation alignment of small grains in the process. The PL peak energies of the PbSe layers as well as the PbSe dendrites and the cubes agreed well with their absorption edges in the transmission spectra, indicating that the photoluminescence originates from the band-edge emission. The band-edge emissions hold promise for the development of potential mid-infrared light sources using PbSe fabricated by these methods.",

keywords = "FWHM, carrier-phonon interaction, lead selenide, mid-infrared, photoluminescence, selenization",

author = "Jungdong Kim and Ahn, {Hak Young} and Kim, {Seung Gi} and Eunsoon Oh and Ju, {Byeong Kwon} and Choi, {Won Jun} and Cho, {So Hye}",

note = "Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2015052280), by Chungnam National University and by the Korea Institute of Science and Technology (project No. 2E26120). Publisher Copyright: {\textcopyright} 2016 IOP Publishing Ltd.",

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AU - Oh, Eunsoon

AU - Ju, Byeong Kwon

AU - Choi, Won Jun

AU - Cho, So Hye

N1 - Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2015052280), by Chungnam National University and by the Korea Institute of Science and Technology (project No. 2E26120). Publisher Copyright: © 2016 IOP Publishing Ltd.

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N2 - We studied temperature-dependent photoluminescence (PL) spectra of lead selenide (PbSe) dendrites and cubes grown by a solvothermal method. Their PL peaks were located at ∼8 μm at 10 K with a full width at half maximum (FWHM) of 10 meV. Using the temperature-dependent FWHM values, we obtained carrier-phonon coupling coefficients for PbSe. We also demonstrated mechanochemical synthesis of polycrystalline PbS nanoparticles and their successful conversion into a PbSe layer composed of nanocrystals by a selenization process with thermal treatment. The nanocrystals were found to be formed by the orientation alignment of small grains in the process. The PL peak energies of the PbSe layers as well as the PbSe dendrites and the cubes agreed well with their absorption edges in the transmission spectra, indicating that the photoluminescence originates from the band-edge emission. The band-edge emissions hold promise for the development of potential mid-infrared light sources using PbSe fabricated by these methods.

AB - We studied temperature-dependent photoluminescence (PL) spectra of lead selenide (PbSe) dendrites and cubes grown by a solvothermal method. Their PL peaks were located at ∼8 μm at 10 K with a full width at half maximum (FWHM) of 10 meV. Using the temperature-dependent FWHM values, we obtained carrier-phonon coupling coefficients for PbSe. We also demonstrated mechanochemical synthesis of polycrystalline PbS nanoparticles and their successful conversion into a PbSe layer composed of nanocrystals by a selenization process with thermal treatment. The nanocrystals were found to be formed by the orientation alignment of small grains in the process. The PL peak energies of the PbSe layers as well as the PbSe dendrites and the cubes agreed well with their absorption edges in the transmission spectra, indicating that the photoluminescence originates from the band-edge emission. The band-edge emissions hold promise for the development of potential mid-infrared light sources using PbSe fabricated by these methods.

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Photoluminescence properties of lead selenide produced by selenization and a solvothermal method

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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