Photoluminescence properties of (Y1-x-yMxEuy)BO3 (M = Al, Zn, and La) phosphors prepared by ultrasonic spray pyrolysis under VUV excitation

J. H. Lee, M. H. Heo, S. J. Kim, S. Nahm, K. Park

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    22 Citations (Scopus)

    Abstract

    The red-emitting (Y1-x-yMxEuy)BO3 (M = Al, Zn, and La, 0 ≤ x ≤ 0.1, 0.04 ≤ y ≤ 0.16) phosphors were synthesized by ultrasonic spray pyrolysis and their photoluminescence characteristics were studied under VUV excitation. The emission intensity was significantly improved by adding metal (M) dopants because they acted as an intermediator for the transfer of excitation energy from the host lattice to the activator Eu3+. The emission intensity of the (Y0.94-xMxEu0.06)BO3 increased up to x = 0.025 with increasing metal concentration and then decreased with a further increase in metal concentration owing to the concentration quenching effect. The Eu3+- and Al3+-co-doped (Y0.975-yAl0.025Euy)BO3 showed the highest emission intensity at a lower Eu content (y = 0.06), when compared to that (y = 0.13) of singly Eu3+-doped (Y1-yEuy)BO3 because of the sensitization effect of Al3+ ions.

    Original languageEnglish
    Pages (from-to)272-274
    Number of pages3
    JournalJournal of Alloys and Compounds
    Volume473
    Issue number1-2
    DOIs
    Publication statusPublished - 2009 Apr 3

    Keywords

    • Ceramics
    • Inorganic materials
    • Luminescence
    • Optical properties

    ASJC Scopus subject areas

    • Mechanics of Materials
    • Mechanical Engineering
    • Metals and Alloys
    • Materials Chemistry

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