Photopatternability of poly(vinylcarbazole) bearing cinnamate pendants and its blends with a soluble poly(p-phenylene vinylene) derivative

Young Jun Yu; Seung Hun Lee; Dong Hoon Choi; Jung Il Jin; Nir Tessler

doi:10.1007/BF03218765

Photopatternability of poly(vinylcarbazole) bearing cinnamate pendants and its blends with a soluble poly(p-phenylene vinylene) derivative

Young Jun Yu, Seung Hun Lee, Dong Hoon Choi, Jung Il Jin, Nir Tessler

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Poly[(1-(9-carbazolyl)ethylene)-co-(3-cinnamoyloxyoctyl-9-carbazolyl)] ethylene (PVK-Cin) was prepared by tethering cinnamate pendants to a carbazole group via an octylene spacer. The photopatternability of the new PVK based-polymer was investigated using a photocrosslinking reaction under UV light illumination (λ = 254 nm). Blends of the PVK-Cin and a soluble poly(phenylene vinylene) (CzEh-PPV) were employed to study the photocrosslinking behavior. Well resolved lithographic patterns were observed in these polymer systems. PVK-Cin produced a blue light emitting pattern both before and after the photocrosslinking reaction. The blends of PVK-Cin and CzEh-PPV also showed corresponding emissions at 398 and 525 (560) nm in the film state.

Original language	English
Pages (from-to)	142-146
Number of pages	5
Journal	Macromolecular Research
Volume	15
Issue number	2
DOIs	https://doi.org/10.1007/BF03218765
Publication status	Published - 2007 Mar

Keywords

Carbazole
Cinnamate
PPV
Photopatterning
Poly(vinylcarbazole)

ASJC Scopus subject areas

Chemical Engineering(all)
Organic Chemistry
Polymers and Plastics
Materials Chemistry

Access to Document

10.1007/BF03218765

Cite this

@article{16adec067a954757b7de06fefa343c3d,

title = "Photopatternability of poly(vinylcarbazole) bearing cinnamate pendants and its blends with a soluble poly(p-phenylene vinylene) derivative",

abstract = "Poly[(1-(9-carbazolyl)ethylene)-co-(3-cinnamoyloxyoctyl-9-carbazolyl)] ethylene (PVK-Cin) was prepared by tethering cinnamate pendants to a carbazole group via an octylene spacer. The photopatternability of the new PVK based-polymer was investigated using a photocrosslinking reaction under UV light illumination (λ = 254 nm). Blends of the PVK-Cin and a soluble poly(phenylene vinylene) (CzEh-PPV) were employed to study the photocrosslinking behavior. Well resolved lithographic patterns were observed in these polymer systems. PVK-Cin produced a blue light emitting pattern both before and after the photocrosslinking reaction. The blends of PVK-Cin and CzEh-PPV also showed corresponding emissions at 398 and 525 (560) nm in the film state.",

keywords = "Carbazole, Cinnamate, PPV, Photopatterning, Poly(vinylcarbazole)",

author = "Yu, {Young Jun} and Lee, {Seung Hun} and Choi, {Dong Hoon} and Jin, {Jung Il} and Nir Tessler",

year = "2007",

month = mar,

doi = "10.1007/BF03218765",

language = "English",

volume = "15",

pages = "142--146",

journal = "Macromolecular Research",

issn = "1598-5032",

publisher = "Polymer Society of Korea",

number = "2",

}

TY - JOUR

T1 - Photopatternability of poly(vinylcarbazole) bearing cinnamate pendants and its blends with a soluble poly(p-phenylene vinylene) derivative

AU - Yu, Young Jun

AU - Lee, Seung Hun

AU - Choi, Dong Hoon

AU - Jin, Jung Il

AU - Tessler, Nir

PY - 2007/3

Y1 - 2007/3

N2 - Poly[(1-(9-carbazolyl)ethylene)-co-(3-cinnamoyloxyoctyl-9-carbazolyl)] ethylene (PVK-Cin) was prepared by tethering cinnamate pendants to a carbazole group via an octylene spacer. The photopatternability of the new PVK based-polymer was investigated using a photocrosslinking reaction under UV light illumination (λ = 254 nm). Blends of the PVK-Cin and a soluble poly(phenylene vinylene) (CzEh-PPV) were employed to study the photocrosslinking behavior. Well resolved lithographic patterns were observed in these polymer systems. PVK-Cin produced a blue light emitting pattern both before and after the photocrosslinking reaction. The blends of PVK-Cin and CzEh-PPV also showed corresponding emissions at 398 and 525 (560) nm in the film state.

AB - Poly[(1-(9-carbazolyl)ethylene)-co-(3-cinnamoyloxyoctyl-9-carbazolyl)] ethylene (PVK-Cin) was prepared by tethering cinnamate pendants to a carbazole group via an octylene spacer. The photopatternability of the new PVK based-polymer was investigated using a photocrosslinking reaction under UV light illumination (λ = 254 nm). Blends of the PVK-Cin and a soluble poly(phenylene vinylene) (CzEh-PPV) were employed to study the photocrosslinking behavior. Well resolved lithographic patterns were observed in these polymer systems. PVK-Cin produced a blue light emitting pattern both before and after the photocrosslinking reaction. The blends of PVK-Cin and CzEh-PPV also showed corresponding emissions at 398 and 525 (560) nm in the film state.

KW - Carbazole

KW - Cinnamate

KW - PPV

KW - Photopatterning

KW - Poly(vinylcarbazole)

UR - http://www.scopus.com/inward/record.url?scp=34247100155&partnerID=8YFLogxK

U2 - 10.1007/BF03218765

DO - 10.1007/BF03218765

M3 - Article

AN - SCOPUS:34247100155

SN - 1598-5032

VL - 15

SP - 142

EP - 146

JO - Macromolecular Research

JF - Macromolecular Research

IS - 2

ER -

Photopatternability of poly(vinylcarbazole) bearing cinnamate pendants and its blends with a soluble poly(p-phenylene vinylene) derivative

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this