Polarization-controlled chiroptical and 2D optical spectroscopy

Kyungwon Kwak; Kwang Hee Park; Minhaeng Cho

doi:10.1201/b13972

Polarization-controlled chiroptical and 2D optical spectroscopy

Kyungwon Kwak, Kwang Hee Park, Minhaeng Cho

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

On a microscopic level, many molecular processes occur on femtosecond (10-15 s) and picosecond (10^-12 s) timescales. For example, electron and proton transfers take place in a few femtoseconds and picoseconds, respectively. Water molecules reorient in a few picoseconds in liquids and exchange their hydrogen-bond partners in several picoseconds in aqueous solutions [1,2]. Carbon-carbon bond rotates in tens of picoseconds [3]. Solvent molecules around a solute can reorganize on subpicosecond and picosecond timescales upon an electronic perturbation of the solute [4,5].

Original language	English
Title of host publication	Ultrafast Infrared Vibrational Spectroscopy
Publisher	CRC Press
Pages	203-238
Number of pages	36
ISBN (Electronic)	9781466510142
ISBN (Print)	9781466510135
DOIs	https://doi.org/10.1201/b13972
Publication status	Published - 2013 Jan 1

ASJC Scopus subject areas

General Physics and Astronomy
General Engineering
General Chemistry

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abstract = "On a microscopic level, many molecular processes occur on femtosecond (10-15 s) and picosecond (10-12 s) timescales. For example, electron and proton transfers take place in a few femtoseconds and picoseconds, respectively. Water molecules reorient in a few picoseconds in liquids and exchange their hydrogen-bond partners in several picoseconds in aqueous solutions [1,2]. Carbon-carbon bond rotates in tens of picoseconds [3]. Solvent molecules around a solute can reorganize on subpicosecond and picosecond timescales upon an electronic perturbation of the solute [4,5].",

author = "Kyungwon Kwak and Park, {Kwang Hee} and Minhaeng Cho",

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doi = "10.1201/b13972",

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N2 - On a microscopic level, many molecular processes occur on femtosecond (10-15 s) and picosecond (10-12 s) timescales. For example, electron and proton transfers take place in a few femtoseconds and picoseconds, respectively. Water molecules reorient in a few picoseconds in liquids and exchange their hydrogen-bond partners in several picoseconds in aqueous solutions [1,2]. Carbon-carbon bond rotates in tens of picoseconds [3]. Solvent molecules around a solute can reorganize on subpicosecond and picosecond timescales upon an electronic perturbation of the solute [4,5].

AB - On a microscopic level, many molecular processes occur on femtosecond (10-15 s) and picosecond (10-12 s) timescales. For example, electron and proton transfers take place in a few femtoseconds and picoseconds, respectively. Water molecules reorient in a few picoseconds in liquids and exchange their hydrogen-bond partners in several picoseconds in aqueous solutions [1,2]. Carbon-carbon bond rotates in tens of picoseconds [3]. Solvent molecules around a solute can reorganize on subpicosecond and picosecond timescales upon an electronic perturbation of the solute [4,5].

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Polarization-controlled chiroptical and 2D optical spectroscopy

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