Poly(2,5-thienylene vinylene) in nano shapes by CVD polymerization

Ki Ryong Lee; Young Jun Yu; Sung Hoon Joo; Chun Young Lee; Dong Hoon Choi; Jin Soo Joo; Young Sup Park; Jung Il Jin

doi:10.1002/marc.200700004

Poly(2,5-thienylene vinylene) in nano shapes by CVD polymerization

Ki Ryong Lee, Young Jun Yu, Sung Hoon Joo, Chun Young Lee, Dong Hoon Choi, Jin Soo Joo, Young Sup Park, Jung Il Jin

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Poly(2,5-thienylene vinylene) (PTV), an insoluble conjugated polymer, can be readily prepared in various shapes of different nanodimensions by the chemical vapor deposition polymerization of 2,5-bis(chloromethyl)thiophene. The bischloromethyl monomer in the vapor phase is activated at 600°C. The activated monomer vapor is deposited at room temperature on the surface of various substrates to prepare polymeric films, fibers, tubes etc., which are then thermally converted into PTV. PTV thin films can be carbonized thermally to produce graphitic compositions that contain sulfur atoms. Electrical conductivities of FeCl₄^--doped PTV and carbonized films are reported.

Original language	English
Pages (from-to)	1057-1061
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	28
Issue number	9
DOIs	https://doi.org/10.1002/marc.200700004
Publication status	Published - 2007 May 2

Keywords

2,5-bis(chloromethyl)thiophene
Chemical vapor deposition polymerization
Nanodimension
Raman spectroscopy
TEM

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/marc.200700004

Cite this

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title = "Poly(2,5-thienylene vinylene) in nano shapes by CVD polymerization",

abstract = "Poly(2,5-thienylene vinylene) (PTV), an insoluble conjugated polymer, can be readily prepared in various shapes of different nanodimensions by the chemical vapor deposition polymerization of 2,5-bis(chloromethyl)thiophene. The bischloromethyl monomer in the vapor phase is activated at 600°C. The activated monomer vapor is deposited at room temperature on the surface of various substrates to prepare polymeric films, fibers, tubes etc., which are then thermally converted into PTV. PTV thin films can be carbonized thermally to produce graphitic compositions that contain sulfur atoms. Electrical conductivities of FeCl4--doped PTV and carbonized films are reported.",

keywords = "2,5-bis(chloromethyl)thiophene, Chemical vapor deposition polymerization, Nanodimension, Raman spectroscopy, TEM",

author = "Lee, {Ki Ryong} and Yu, {Young Jun} and Joo, {Sung Hoon} and Lee, {Chun Young} and Choi, {Dong Hoon} and Joo, {Jin Soo} and Park, {Young Sup} and Jin, {Jung Il}",

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language = "English",

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publisher = "Wiley-VCH Verlag",

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T1 - Poly(2,5-thienylene vinylene) in nano shapes by CVD polymerization

AU - Lee, Ki Ryong

AU - Yu, Young Jun

AU - Joo, Sung Hoon

AU - Lee, Chun Young

AU - Choi, Dong Hoon

AU - Joo, Jin Soo

AU - Park, Young Sup

AU - Jin, Jung Il

PY - 2007/5/2

Y1 - 2007/5/2

N2 - Poly(2,5-thienylene vinylene) (PTV), an insoluble conjugated polymer, can be readily prepared in various shapes of different nanodimensions by the chemical vapor deposition polymerization of 2,5-bis(chloromethyl)thiophene. The bischloromethyl monomer in the vapor phase is activated at 600°C. The activated monomer vapor is deposited at room temperature on the surface of various substrates to prepare polymeric films, fibers, tubes etc., which are then thermally converted into PTV. PTV thin films can be carbonized thermally to produce graphitic compositions that contain sulfur atoms. Electrical conductivities of FeCl4--doped PTV and carbonized films are reported.

AB - Poly(2,5-thienylene vinylene) (PTV), an insoluble conjugated polymer, can be readily prepared in various shapes of different nanodimensions by the chemical vapor deposition polymerization of 2,5-bis(chloromethyl)thiophene. The bischloromethyl monomer in the vapor phase is activated at 600°C. The activated monomer vapor is deposited at room temperature on the surface of various substrates to prepare polymeric films, fibers, tubes etc., which are then thermally converted into PTV. PTV thin films can be carbonized thermally to produce graphitic compositions that contain sulfur atoms. Electrical conductivities of FeCl4--doped PTV and carbonized films are reported.

KW - 2,5-bis(chloromethyl)thiophene

KW - Chemical vapor deposition polymerization

KW - Nanodimension

KW - Raman spectroscopy

KW - TEM

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DO - 10.1002/marc.200700004

M3 - Article

AN - SCOPUS:34547900703

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JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 9

ER -

Poly(2,5-thienylene vinylene) in nano shapes by CVD polymerization

Abstract

Keywords

ASJC Scopus subject areas

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