Poly(ionic liquid)-stabilized graphene sheets and their hybrid with poly(3,4-ethylenedioxythiophene)

Tran Thanh Tung; Tae Young Kim; Jong Pil Shim; Woo Seok Yang; Hyeongkeun Kim; Kwang S. Suh

doi:10.1016/j.orgel.2011.09.012

Poly(ionic liquid)-stabilized graphene sheets and their hybrid with poly(3,4-ethylenedioxythiophene)

Tran Thanh Tung, Tae Young Kim, Jong Pil Shim, Woo Seok Yang, Hyeongkeun Kim, Kwang S. Suh

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

Hybrid materials of reduced graphene oxide (RG-O) and poly(3,4- ethylenedioxythiophene) (PEDOT) were prepared by poly(ionic liquid)-mediated hybridization. In this hybrid material, poly(ionic liquid)s (PILs) are found to be preferentially physisorbed onto the RG-O platelets, and allow them to be dispersed as a homogeneous colloidal system. In addition to the function as an effective stabilizer, the PIL also promotes PEDOT growth on RG-O platelets through favorable molecular interaction of PIL with PEDOT chains. The resulting material, a hybrid of RG-O and PEDOT showed an electrical conductivity of 18.8 S/cm at a RG-O loading of 0.3 wt.%, and its thin film on glass substrate showed a surface resistivity as low as 1.8 × 10⁴ /sq at an optical transmittance of 91.18%.

Original language	English
Pages (from-to)	2215-2224
Number of pages	10
Journal	Organic Electronics
Volume	12
Issue number	12
DOIs	https://doi.org/10.1016/j.orgel.2011.09.012
Publication status	Published - 2011 Dec

Bibliographical note

Funding Information:
This work was supported by InsCon Tech. Co. Ltd., Korea, and Korea Ministry of Environment as the Eco-Innovation Project (Global-Top Project).

Keywords

Conducting polymer
Graphene
Hybrid composites
Poly(ionic liquid)
Transparent conductive film

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Condensed Matter Physics
Materials Chemistry
Electrical and Electronic Engineering
Biomaterials

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10.1016/j.orgel.2011.09.012

Cite this

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title = "Poly(ionic liquid)-stabilized graphene sheets and their hybrid with poly(3,4-ethylenedioxythiophene)",

abstract = "Hybrid materials of reduced graphene oxide (RG-O) and poly(3,4- ethylenedioxythiophene) (PEDOT) were prepared by poly(ionic liquid)-mediated hybridization. In this hybrid material, poly(ionic liquid)s (PILs) are found to be preferentially physisorbed onto the RG-O platelets, and allow them to be dispersed as a homogeneous colloidal system. In addition to the function as an effective stabilizer, the PIL also promotes PEDOT growth on RG-O platelets through favorable molecular interaction of PIL with PEDOT chains. The resulting material, a hybrid of RG-O and PEDOT showed an electrical conductivity of 18.8 S/cm at a RG-O loading of 0.3 wt.%, and its thin film on glass substrate showed a surface resistivity as low as 1.8 × 104 /sq at an optical transmittance of 91.18%.",

keywords = "Conducting polymer, Graphene, Hybrid composites, Poly(ionic liquid), Transparent conductive film",

author = "Tung, {Tran Thanh} and Kim, {Tae Young} and Shim, {Jong Pil} and Yang, {Woo Seok} and Hyeongkeun Kim and Suh, {Kwang S.}",

note = "Funding Information: This work was supported by InsCon Tech. Co. Ltd., Korea, and Korea Ministry of Environment as the Eco-Innovation Project (Global-Top Project). ",

year = "2011",

month = dec,

doi = "10.1016/j.orgel.2011.09.012",

language = "English",

volume = "12",

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T1 - Poly(ionic liquid)-stabilized graphene sheets and their hybrid with poly(3,4-ethylenedioxythiophene)

AU - Tung, Tran Thanh

AU - Kim, Tae Young

AU - Shim, Jong Pil

AU - Yang, Woo Seok

AU - Kim, Hyeongkeun

AU - Suh, Kwang S.

N1 - Funding Information: This work was supported by InsCon Tech. Co. Ltd., Korea, and Korea Ministry of Environment as the Eco-Innovation Project (Global-Top Project).

PY - 2011/12

Y1 - 2011/12

N2 - Hybrid materials of reduced graphene oxide (RG-O) and poly(3,4- ethylenedioxythiophene) (PEDOT) were prepared by poly(ionic liquid)-mediated hybridization. In this hybrid material, poly(ionic liquid)s (PILs) are found to be preferentially physisorbed onto the RG-O platelets, and allow them to be dispersed as a homogeneous colloidal system. In addition to the function as an effective stabilizer, the PIL also promotes PEDOT growth on RG-O platelets through favorable molecular interaction of PIL with PEDOT chains. The resulting material, a hybrid of RG-O and PEDOT showed an electrical conductivity of 18.8 S/cm at a RG-O loading of 0.3 wt.%, and its thin film on glass substrate showed a surface resistivity as low as 1.8 × 104 /sq at an optical transmittance of 91.18%.

AB - Hybrid materials of reduced graphene oxide (RG-O) and poly(3,4- ethylenedioxythiophene) (PEDOT) were prepared by poly(ionic liquid)-mediated hybridization. In this hybrid material, poly(ionic liquid)s (PILs) are found to be preferentially physisorbed onto the RG-O platelets, and allow them to be dispersed as a homogeneous colloidal system. In addition to the function as an effective stabilizer, the PIL also promotes PEDOT growth on RG-O platelets through favorable molecular interaction of PIL with PEDOT chains. The resulting material, a hybrid of RG-O and PEDOT showed an electrical conductivity of 18.8 S/cm at a RG-O loading of 0.3 wt.%, and its thin film on glass substrate showed a surface resistivity as low as 1.8 × 104 /sq at an optical transmittance of 91.18%.

KW - Conducting polymer

KW - Graphene

KW - Hybrid composites

KW - Poly(ionic liquid)

KW - Transparent conductive film

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DO - 10.1016/j.orgel.2011.09.012

M3 - Article

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SN - 1566-1199

VL - 12

SP - 2215

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JF - Organic Electronics

IS - 12

ER -

Poly(ionic liquid)-stabilized graphene sheets and their hybrid with poly(3,4-ethylenedioxythiophene)

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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