Potassium ion-selective membrane electrodes based on 1,3-alternate calix[4] crown-5-azacrown-5

Sungeun Kim; Hasuck Kim; Kwan Ho Noh; Seoung Ho Lee; Sung Kuk Kim; Jong Seung Kim

doi:10.1016/S0039-9140(03)00329-1

Potassium ion-selective membrane electrodes based on 1,3-alternate calix[4] crown-5-azacrown-5

Sungeun Kim, Hasuck Kim, Kwan Ho Noh, Seoung Ho Lee, Sung Kuk Kim, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A series of 1,3-alternate calix[4]azacrown ethers for which the monoaza and unsymmetrical crowned-azacrown with different side arms were examined as an ionophore for ion-selective polymeric membrane electrode toward potassium ion. Among them, the electrode based on calix[4] crown-5-azacrown-5 with a phenyl group exhibited near Nernstian response for K⁺ ions over a wide concentration range (1 × 10^-5 to 1 × 10^-1 M) with a limit of detection of 2 × 10^-6 M. It has a fast response time of approximately 2-3 s and can be used for at least 2 months without observing any major deterioration. Selectivity coefficients indicated that interference from all common alkali, alkaline and transition metal ions was very small.

Original language	English
Pages (from-to)	709-716
Number of pages	8
Journal	Talanta
Volume	61
Issue number	5
DOIs	https://doi.org/10.1016/S0039-9140(03)00329-1
Publication status	Published - 2003 Dec 4
Externally published	Yes

Bibliographical note

Funding Information:
The authors wish to acknowledge the financial support of a Grant (No. M20106000044-02B0500-03910 from KISTEP for J.S. Kim and No. R01-1999-000-00036-0 from the Basic Research Program of the KOSEF for H. Kim) and the Center for Molecular Catalysis of Seoul National University.

Keywords

Calix[4]azacrown ether
Potassium ion-selective electrode
Potentiometric detection

ASJC Scopus subject areas

Analytical Chemistry

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10.1016/S0039-9140(03)00329-1

Cite this

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title = "Potassium ion-selective membrane electrodes based on 1,3-alternate calix[4] crown-5-azacrown-5",

abstract = "A series of 1,3-alternate calix[4]azacrown ethers for which the monoaza and unsymmetrical crowned-azacrown with different side arms were examined as an ionophore for ion-selective polymeric membrane electrode toward potassium ion. Among them, the electrode based on calix[4] crown-5-azacrown-5 with a phenyl group exhibited near Nernstian response for K+ ions over a wide concentration range (1 × 10-5 to 1 × 10-1 M) with a limit of detection of 2 × 10-6 M. It has a fast response time of approximately 2-3 s and can be used for at least 2 months without observing any major deterioration. Selectivity coefficients indicated that interference from all common alkali, alkaline and transition metal ions was very small.",

keywords = "Calix[4]azacrown ether, Potassium ion-selective electrode, Potentiometric detection",

author = "Sungeun Kim and Hasuck Kim and Noh, {Kwan Ho} and Lee, {Seoung Ho} and Kim, {Sung Kuk} and Kim, {Jong Seung}",

note = "Funding Information: The authors wish to acknowledge the financial support of a Grant (No. M20106000044-02B0500-03910 from KISTEP for J.S. Kim and No. R01-1999-000-00036-0 from the Basic Research Program of the KOSEF for H. Kim) and the Center for Molecular Catalysis of Seoul National University. ",

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doi = "10.1016/S0039-9140(03)00329-1",

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AU - Kim, Sungeun

AU - Kim, Hasuck

AU - Noh, Kwan Ho

AU - Lee, Seoung Ho

AU - Kim, Sung Kuk

AU - Kim, Jong Seung

N1 - Funding Information: The authors wish to acknowledge the financial support of a Grant (No. M20106000044-02B0500-03910 from KISTEP for J.S. Kim and No. R01-1999-000-00036-0 from the Basic Research Program of the KOSEF for H. Kim) and the Center for Molecular Catalysis of Seoul National University.

PY - 2003/12/4

Y1 - 2003/12/4

N2 - A series of 1,3-alternate calix[4]azacrown ethers for which the monoaza and unsymmetrical crowned-azacrown with different side arms were examined as an ionophore for ion-selective polymeric membrane electrode toward potassium ion. Among them, the electrode based on calix[4] crown-5-azacrown-5 with a phenyl group exhibited near Nernstian response for K+ ions over a wide concentration range (1 × 10-5 to 1 × 10-1 M) with a limit of detection of 2 × 10-6 M. It has a fast response time of approximately 2-3 s and can be used for at least 2 months without observing any major deterioration. Selectivity coefficients indicated that interference from all common alkali, alkaline and transition metal ions was very small.

AB - A series of 1,3-alternate calix[4]azacrown ethers for which the monoaza and unsymmetrical crowned-azacrown with different side arms were examined as an ionophore for ion-selective polymeric membrane electrode toward potassium ion. Among them, the electrode based on calix[4] crown-5-azacrown-5 with a phenyl group exhibited near Nernstian response for K+ ions over a wide concentration range (1 × 10-5 to 1 × 10-1 M) with a limit of detection of 2 × 10-6 M. It has a fast response time of approximately 2-3 s and can be used for at least 2 months without observing any major deterioration. Selectivity coefficients indicated that interference from all common alkali, alkaline and transition metal ions was very small.

KW - Calix[4]azacrown ether

KW - Potassium ion-selective electrode

KW - Potentiometric detection

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SN - 0039-9140

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IS - 5

ER -

Potassium ion-selective membrane electrodes based on 1,3-alternate calix[4] crown-5-azacrown-5

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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