Preparation, characterization and performance of poly(aylene ether sulfone)/modified silica nanocomposite reverse osmosis membrane for seawater desalination

Sang Gon Kim; Jeong Hwan Chun; Byung Hee Chun; Sung Hyun Kim

doi:10.1016/j.desal.2013.06.017

Preparation, characterization and performance of poly(aylene ether sulfone)/modified silica nanocomposite reverse osmosis membrane for seawater desalination

Sang Gon Kim
, Jeong Hwan Chun
, Byung Hee Chun
, Sung Hyun Kim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

In this paper, composite reverse osmosis (RO) membranes made from sulfonated poly(arylene ether sulfone) containing amino groups (aPES) and hyper-branched aromatic polyamide-grafted silica (HBP-g-silica) were prepared, with the aim of enhancing chlorination resistance and improving membrane performance. The performance of the RO membranes containing aPES and HBP-g-silica was evaluated; the salt rejection and water flux were 96% and 34L/m²/h, respectively. After the chlorination test, the salt rejection decreased by only 14% and the water flux increased by 4L/m²/h. The aPES/HBP-g-silica significantly modified the three-dimensional polyamide (PA) network structures and contributed to the high performance because of the chain stiffness of the copolymer with a high degree of cross-linking in the RO membranes. Therefore, the aPES and HBP-g-silica, which helped improve water permeability, also protected the active layer structure from degradation and enhanced the chlorine resistance of the RO membrane.

Original language	English
Pages (from-to)	76-83
Number of pages	8
Journal	Desalination
Volume	325
DOIs	https://doi.org/10.1016/j.desal.2013.06.017
Publication status	Published - 2013 Sept 16

Bibliographical note

Funding Information:
This work was supported by a grant from the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (20114010203050) funded by the Korean government Ministry of Knowledge Economy .

Funding Information:
This research was supported by a grant (# 12 seaHERO B02-06 ) from the Plant Technology Advancement Program funded by the Ministry of Land, Transport and Maritime Affairs of the Korean government .

Copyright:
Copyright 2013 Elsevier B.V., All rights reserved.

Keywords

Chlorine resistance
Desalination
Nanoparticle
Reverse osmosis
Sulfonated poly(arylene ether sulfone)

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
General Materials Science
Water Science and Technology
Mechanical Engineering

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10.1016/j.desal.2013.06.017

Cite this

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title = "Preparation, characterization and performance of poly(aylene ether sulfone)/modified silica nanocomposite reverse osmosis membrane for seawater desalination",

abstract = "In this paper, composite reverse osmosis (RO) membranes made from sulfonated poly(arylene ether sulfone) containing amino groups (aPES) and hyper-branched aromatic polyamide-grafted silica (HBP-g-silica) were prepared, with the aim of enhancing chlorination resistance and improving membrane performance. The performance of the RO membranes containing aPES and HBP-g-silica was evaluated; the salt rejection and water flux were 96\% and 34L/m2/h, respectively. After the chlorination test, the salt rejection decreased by only 14\% and the water flux increased by 4L/m2/h. The aPES/HBP-g-silica significantly modified the three-dimensional polyamide (PA) network structures and contributed to the high performance because of the chain stiffness of the copolymer with a high degree of cross-linking in the RO membranes. Therefore, the aPES and HBP-g-silica, which helped improve water permeability, also protected the active layer structure from degradation and enhanced the chlorine resistance of the RO membrane.",

keywords = "Chlorine resistance, Desalination, Nanoparticle, Reverse osmosis, Sulfonated poly(arylene ether sulfone)",

author = "Kim, \{Sang Gon\} and Chun, \{Jeong Hwan\} and Chun, \{Byung Hee\} and Kim, \{Sung Hyun\}",

note = "Funding Information: This work was supported by a grant from the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (20114010203050) funded by the Korean government Ministry of Knowledge Economy . Funding Information: This research was supported by a grant (\# 12 seaHERO B02-06 ) from the Plant Technology Advancement Program funded by the Ministry of Land, Transport and Maritime Affairs of the Korean government . Copyright: Copyright 2013 Elsevier B.V., All rights reserved.",

year = "2013",

month = sep,

day = "16",

doi = "10.1016/j.desal.2013.06.017",

language = "English",

volume = "325",

pages = "76--83",

journal = "Desalination",

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AU - Kim, Sang Gon

AU - Chun, Jeong Hwan

AU - Chun, Byung Hee

AU - Kim, Sung Hyun

N1 - Funding Information: This work was supported by a grant from the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (20114010203050) funded by the Korean government Ministry of Knowledge Economy . Funding Information: This research was supported by a grant (# 12 seaHERO B02-06 ) from the Plant Technology Advancement Program funded by the Ministry of Land, Transport and Maritime Affairs of the Korean government . Copyright: Copyright 2013 Elsevier B.V., All rights reserved.

PY - 2013/9/16

Y1 - 2013/9/16

N2 - In this paper, composite reverse osmosis (RO) membranes made from sulfonated poly(arylene ether sulfone) containing amino groups (aPES) and hyper-branched aromatic polyamide-grafted silica (HBP-g-silica) were prepared, with the aim of enhancing chlorination resistance and improving membrane performance. The performance of the RO membranes containing aPES and HBP-g-silica was evaluated; the salt rejection and water flux were 96% and 34L/m2/h, respectively. After the chlorination test, the salt rejection decreased by only 14% and the water flux increased by 4L/m2/h. The aPES/HBP-g-silica significantly modified the three-dimensional polyamide (PA) network structures and contributed to the high performance because of the chain stiffness of the copolymer with a high degree of cross-linking in the RO membranes. Therefore, the aPES and HBP-g-silica, which helped improve water permeability, also protected the active layer structure from degradation and enhanced the chlorine resistance of the RO membrane.

AB - In this paper, composite reverse osmosis (RO) membranes made from sulfonated poly(arylene ether sulfone) containing amino groups (aPES) and hyper-branched aromatic polyamide-grafted silica (HBP-g-silica) were prepared, with the aim of enhancing chlorination resistance and improving membrane performance. The performance of the RO membranes containing aPES and HBP-g-silica was evaluated; the salt rejection and water flux were 96% and 34L/m2/h, respectively. After the chlorination test, the salt rejection decreased by only 14% and the water flux increased by 4L/m2/h. The aPES/HBP-g-silica significantly modified the three-dimensional polyamide (PA) network structures and contributed to the high performance because of the chain stiffness of the copolymer with a high degree of cross-linking in the RO membranes. Therefore, the aPES and HBP-g-silica, which helped improve water permeability, also protected the active layer structure from degradation and enhanced the chlorine resistance of the RO membrane.

KW - Chlorine resistance

KW - Desalination

KW - Nanoparticle

KW - Reverse osmosis

KW - Sulfonated poly(arylene ether sulfone)

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DO - 10.1016/j.desal.2013.06.017

M3 - Article

AN - SCOPUS:84880980211

SN - 0011-9164

VL - 325

SP - 76

EP - 83

JO - Desalination

JF - Desalination

ER -

Preparation, characterization and performance of poly(aylene ether sulfone)/modified silica nanocomposite reverse osmosis membrane for seawater desalination

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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