Preparation of a Cyclopentadienyl Ligand from the Pauson-Khand Reaction Product and Its Use in Complex Chemistry

Bun Yeoul Lee; Hyungjoon Moon; Young Keun Chung; Nackcheol Jeong; G. B. Carpenter

doi:10.1021/om00034a021

Preparation of a Cyclopentadienyl Ligand from the Pauson-Khand Reaction Product and Its Use in Complex Chemistry

Bun Yeoul Lee, Hyungjoon Moon, Young Keun Chung, Nackcheol Jeong, G. B. Carpenter

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

From the Pauson-Khand products 1 and 5 as starting materials, the novel cyclopentadiene compounds 3 and 7 were prepared efficiently. Metalation of 3 with Mn₂(CO)₁₀ resulted in a new bicyclic pentadienylmanganese compound, 4. Reaction of 7 with M₂(CO)₁₀ (M = Mn, Re) and Fe₂(CO)₉ gave the corresponding organometallic compounds 9–12. 7 also reacts with KH to produce the cyclopentadienide anion 8, which reacts with M(CO)₃(CH₃CN)₃ (M = Cr, W), Mo(CO)₆, and FeCl₃ to yield compounds 13–16. The molecular structures of 9 and 16 have been determined.

Original language	English
Pages (from-to)	3879-3884
Number of pages	6
Journal	Organometallics
Volume	12
Issue number	10
DOIs	https://doi.org/10.1021/om00034a021
Publication status	Published - 1993

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om00034a021

Cite this

@article{79344cc2deac494090e21185e0aebf3d,

title = "Preparation of a Cyclopentadienyl Ligand from the Pauson-Khand Reaction Product and Its Use in Complex Chemistry",

abstract = "From the Pauson-Khand products 1 and 5 as starting materials, the novel cyclopentadiene compounds 3 and 7 were prepared efficiently. Metalation of 3 with Mn2(CO)10 resulted in a new bicyclic pentadienylmanganese compound, 4. Reaction of 7 with M2(CO)10 (M = Mn, Re) and Fe2(CO)9 gave the corresponding organometallic compounds 9–12. 7 also reacts with KH to produce the cyclopentadienide anion 8, which reacts with M(CO)3(CH3CN)3 (M = Cr, W), Mo(CO)6, and FeCl3 to yield compounds 13–16. The molecular structures of 9 and 16 have been determined.",

author = "Lee, {Bun Yeoul} and Hyungjoon Moon and Chung, {Young Keun} and Nackcheol Jeong and Carpenter, {G. B.}",

year = "1993",

doi = "10.1021/om00034a021",

language = "English",

volume = "12",

pages = "3879--3884",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Preparation of a Cyclopentadienyl Ligand from the Pauson-Khand Reaction Product and Its Use in Complex Chemistry

AU - Lee, Bun Yeoul

AU - Moon, Hyungjoon

AU - Chung, Young Keun

AU - Jeong, Nackcheol

AU - Carpenter, G. B.

PY - 1993

Y1 - 1993

N2 - From the Pauson-Khand products 1 and 5 as starting materials, the novel cyclopentadiene compounds 3 and 7 were prepared efficiently. Metalation of 3 with Mn2(CO)10 resulted in a new bicyclic pentadienylmanganese compound, 4. Reaction of 7 with M2(CO)10 (M = Mn, Re) and Fe2(CO)9 gave the corresponding organometallic compounds 9–12. 7 also reacts with KH to produce the cyclopentadienide anion 8, which reacts with M(CO)3(CH3CN)3 (M = Cr, W), Mo(CO)6, and FeCl3 to yield compounds 13–16. The molecular structures of 9 and 16 have been determined.

AB - From the Pauson-Khand products 1 and 5 as starting materials, the novel cyclopentadiene compounds 3 and 7 were prepared efficiently. Metalation of 3 with Mn2(CO)10 resulted in a new bicyclic pentadienylmanganese compound, 4. Reaction of 7 with M2(CO)10 (M = Mn, Re) and Fe2(CO)9 gave the corresponding organometallic compounds 9–12. 7 also reacts with KH to produce the cyclopentadienide anion 8, which reacts with M(CO)3(CH3CN)3 (M = Cr, W), Mo(CO)6, and FeCl3 to yield compounds 13–16. The molecular structures of 9 and 16 have been determined.

UR - http://www.scopus.com/inward/record.url?scp=0000130227&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000130227&partnerID=8YFLogxK

U2 - 10.1021/om00034a021

DO - 10.1021/om00034a021

M3 - Article

AN - SCOPUS:0000130227

SN - 0276-7333

VL - 12

SP - 3879

EP - 3884

JO - Organometallics

JF - Organometallics

IS - 10

ER -

Preparation of a Cyclopentadienyl Ligand from the Pauson-Khand Reaction Product and Its Use in Complex Chemistry

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this