Abstract
The new alloying method has been suggested to synthesis Ni-Al alloy powder using AlCl3 as an activator at relatively low 500~600°C under vacuum condition. The used AlCl3 served as the catalyst, promoting the reaction between Ni and Al powder and lowering the fabrication temperature by 900~1,000°C compared with that of the conventional process. Ni-Al alloy properties prepared by varying parameters were investigated and the as prepared Ni-Al alloys were alkali leached by NaOH solution for surface modification to enhance the specific surface area. The methane steam reforming activity tests were performed at temperature range of 600~850°C to investigate the possibility in fuel cell system as the catalysts. As results, it was confirmed that leached Ni50Al alloy shows as good methane conversion and long term stability as that of commercial catalyst and superior H2 yield at low temperature of 600~750°C.
Original language | English |
---|---|
Title of host publication | EFC 2013 - Proceedings of the 5th European Fuel Cell Piero Lunghi Conference |
Publisher | ENEA |
Pages | 311-312 |
Number of pages | 2 |
ISBN (Print) | 9788882862978 |
Publication status | Published - 2013 |
Event | 5th European Fuel Cell Piero Lunghi Conference and Exhibition, EFC 2013 - Rome, Italy Duration: 2013 Dec 11 → 2013 Dec 13 |
Other
Other | 5th European Fuel Cell Piero Lunghi Conference and Exhibition, EFC 2013 |
---|---|
Country/Territory | Italy |
City | Rome |
Period | 13/12/11 → 13/12/13 |
Keywords
- Aluminum leaching
- Low temperature gas-solid reaction
- Methane steam reforming
- Nickel-aluminum alloy
ASJC Scopus subject areas
- Fuel Technology