Production of bio-jet fuel range alkanes from catalytic deoxygenation of Jatropha fatty acids on a WOx/Pt/TiO2 catalyst

Il Ho Choi; Jin Suk Lee; Chul Ung Kim; Tae Wan Kim; Kwan Young Lee; Kyung Ran Hwang

doi:10.1016/j.fuel.2017.11.094

Production of bio-jet fuel range alkanes from catalytic deoxygenation of Jatropha fatty acids on a WOx/Pt/TiO₂ catalyst

Il Ho Choi
, Jin Suk Lee
, Chul Ung Kim
, Tae Wan Kim
, Kwan Young Lee^*
, Kyung Ran Hwang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

Bio-jet fuel range alkanes were prepared by catalytic deoxygenation reaction of non-edible acid oils with no added hydrogen. A WOx[6]/Pt[1.6]/TiO₂ was used for the deoxygenation of stearic acid and Jatropha fatty acid derived from Jatropha oil by hydrolysis. Tungsten addition to the Pt/TiO₂ showed remarkably enhanced performance, a degree of deoxygenation of 86%, which is more than two times higher than that of the Pt/TiO₂, even though the WOx/TiO₂ had almost no activity for deoxygenation reaction. The enhanced Pt-related hydrogen uptake, measured by H₂-TPR, and XPS analysis showed the intimate contact of tungsten with Pt nanoparticles supported on TiO₂. This tight contact allows for easier C–C cleavage over Pt nanoparticles and this is assisted by the strong bonding between tungsten and oxygen in the reactant, resulting in more C₁₇ hydrocarbon production on the WOx/Pt/TiO₂.

Original language	English
Pages (from-to)	675-685
Number of pages	11
Journal	Fuel
Volume	215
DOIs	https://doi.org/10.1016/j.fuel.2017.11.094
Publication status	Published - 2018 Mar 1

Bibliographical note

Funding Information:
This work was conducted under the framework of the Research and Development Program of the Korea Institute of Energy Research (KIER) ( B7-2432-04 ).

Keywords

Bio-jet fuel
Catalytic deoxygenation
Decarboxylation
Jatropha fatty acids
Oxy-free hydrocarbon

ASJC Scopus subject areas

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology
Organic Chemistry

Access to Document

10.1016/j.fuel.2017.11.094

Cite this

@article{10967975bfe2423cae28f608b3165717,

title = "Production of bio-jet fuel range alkanes from catalytic deoxygenation of Jatropha fatty acids on a WOx/Pt/TiO2 catalyst",

abstract = "Bio-jet fuel range alkanes were prepared by catalytic deoxygenation reaction of non-edible acid oils with no added hydrogen. A WOx[6]/Pt[1.6]/TiO2 was used for the deoxygenation of stearic acid and Jatropha fatty acid derived from Jatropha oil by hydrolysis. Tungsten addition to the Pt/TiO2 showed remarkably enhanced performance, a degree of deoxygenation of 86\%, which is more than two times higher than that of the Pt/TiO2, even though the WOx/TiO2 had almost no activity for deoxygenation reaction. The enhanced Pt-related hydrogen uptake, measured by H2-TPR, and XPS analysis showed the intimate contact of tungsten with Pt nanoparticles supported on TiO2. This tight contact allows for easier C–C cleavage over Pt nanoparticles and this is assisted by the strong bonding between tungsten and oxygen in the reactant, resulting in more C17 hydrocarbon production on the WOx/Pt/TiO2.",

keywords = "Bio-jet fuel, Catalytic deoxygenation, Decarboxylation, Jatropha fatty acids, Oxy-free hydrocarbon",

author = "Choi, \{Il Ho\} and Lee, \{Jin Suk\} and Kim, \{Chul Ung\} and Kim, \{Tae Wan\} and Lee, \{Kwan Young\} and Hwang, \{Kyung Ran\}",

note = "Funding Information: This work was conducted under the framework of the Research and Development Program of the Korea Institute of Energy Research (KIER) ( B7-2432-04 ). ",

year = "2018",

month = mar,

day = "1",

doi = "10.1016/j.fuel.2017.11.094",

language = "English",

volume = "215",

pages = "675--685",

journal = "Fuel",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Production of bio-jet fuel range alkanes from catalytic deoxygenation of Jatropha fatty acids on a WOx/Pt/TiO2 catalyst

AU - Choi, Il Ho

AU - Lee, Jin Suk

AU - Kim, Chul Ung

AU - Kim, Tae Wan

AU - Lee, Kwan Young

AU - Hwang, Kyung Ran

N1 - Funding Information: This work was conducted under the framework of the Research and Development Program of the Korea Institute of Energy Research (KIER) ( B7-2432-04 ).

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Bio-jet fuel range alkanes were prepared by catalytic deoxygenation reaction of non-edible acid oils with no added hydrogen. A WOx[6]/Pt[1.6]/TiO2 was used for the deoxygenation of stearic acid and Jatropha fatty acid derived from Jatropha oil by hydrolysis. Tungsten addition to the Pt/TiO2 showed remarkably enhanced performance, a degree of deoxygenation of 86%, which is more than two times higher than that of the Pt/TiO2, even though the WOx/TiO2 had almost no activity for deoxygenation reaction. The enhanced Pt-related hydrogen uptake, measured by H2-TPR, and XPS analysis showed the intimate contact of tungsten with Pt nanoparticles supported on TiO2. This tight contact allows for easier C–C cleavage over Pt nanoparticles and this is assisted by the strong bonding between tungsten and oxygen in the reactant, resulting in more C17 hydrocarbon production on the WOx/Pt/TiO2.

AB - Bio-jet fuel range alkanes were prepared by catalytic deoxygenation reaction of non-edible acid oils with no added hydrogen. A WOx[6]/Pt[1.6]/TiO2 was used for the deoxygenation of stearic acid and Jatropha fatty acid derived from Jatropha oil by hydrolysis. Tungsten addition to the Pt/TiO2 showed remarkably enhanced performance, a degree of deoxygenation of 86%, which is more than two times higher than that of the Pt/TiO2, even though the WOx/TiO2 had almost no activity for deoxygenation reaction. The enhanced Pt-related hydrogen uptake, measured by H2-TPR, and XPS analysis showed the intimate contact of tungsten with Pt nanoparticles supported on TiO2. This tight contact allows for easier C–C cleavage over Pt nanoparticles and this is assisted by the strong bonding between tungsten and oxygen in the reactant, resulting in more C17 hydrocarbon production on the WOx/Pt/TiO2.

KW - Bio-jet fuel

KW - Catalytic deoxygenation

KW - Decarboxylation

KW - Jatropha fatty acids

KW - Oxy-free hydrocarbon

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