Promoters for the (Alkyne) hexacarbonyldicobalt-Based Cyclopentenone Synthesis

Young Keun Chung; Bun Yeoul Lee; Nakcheol Jeong; Milan Hudecek; Peter L. Pauson

doi:10.1021/om00025a036

Promoters for the (Alkyne) hexacarbonyldicobalt-Based Cyclopentenone Synthesis

Young Keun Chung, Bun Yeoul Lee, Nakcheol Jeong, Milan Hudecek, Peter L. Pauson

Research output: Contribution to journal › Article › peer-review

165 Citations (Scopus)

Abstract

Dimethyl sulfoxide and a variety of other highly polar solvents are shown to promote both inter- and intramolecular cyclopentenone formation from alkenes and (alkyne)hexacarbonyldicobalt complexes. Their use leads to significant changes in both regio- and stereoselectivity when compared to other reaction conditions.

Original language	English
Pages (from-to)	220-223
Number of pages	4
Journal	Organometallics
Volume	12
Issue number	1
DOIs	https://doi.org/10.1021/om00025a036
Publication status	Published - 1993

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00025a036

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title = "Promoters for the (Alkyne) hexacarbonyldicobalt-Based Cyclopentenone Synthesis",

abstract = "Dimethyl sulfoxide and a variety of other highly polar solvents are shown to promote both inter- and intramolecular cyclopentenone formation from alkenes and (alkyne)hexacarbonyldicobalt complexes. Their use leads to significant changes in both regio- and stereoselectivity when compared to other reaction conditions.",

author = "Chung, {Young Keun} and Lee, {Bun Yeoul} and Nakcheol Jeong and Milan Hudecek and Pauson, {Peter L.}",

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AU - Chung, Young Keun

AU - Lee, Bun Yeoul

AU - Jeong, Nakcheol

AU - Hudecek, Milan

AU - Pauson, Peter L.

PY - 1993

Y1 - 1993

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AB - Dimethyl sulfoxide and a variety of other highly polar solvents are shown to promote both inter- and intramolecular cyclopentenone formation from alkenes and (alkyne)hexacarbonyldicobalt complexes. Their use leads to significant changes in both regio- and stereoselectivity when compared to other reaction conditions.

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DO - 10.1021/om00025a036

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SN - 0276-7333

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JF - Organometallics

IS - 1

ER -

Promoters for the (Alkyne) hexacarbonyldicobalt-Based Cyclopentenone Synthesis

Abstract

ASJC Scopus subject areas

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