Properties of cadmium sulfide thin films deposited by chemical bath deposition with ultrasonication

Jun Young Choi, Kang Jin Kim, Ji Beom Yoo, Donghwan Kim

    Research output: Contribution to journalArticlepeer-review

    101 Citations (Scopus)

    Abstract

    Ultrasonic agitation was applied during the chemical bath deposition of CdS thin films. Ultrasonication resulted in a dramatic difference in surface morphology, growth rate, and optical properties of CdS films. There were virtually no colloidal particles adsorbed on the surface. The surface roughness measured by atomic force microscopy was reduced by a factor of two. Band gap energy increased to 2.39 eV from 2.37 eV. X-ray patterns showed that the preferred orientation changed from hexagonal(002)/cubic(111) to hexagonal(101). Optical transmission improved in the wavelength range longer than 520 nm. The chemical reaction for CdS formation started at a lower temperature under ultrasonication, and dense films were obtained even when the chemical composition of the aqueous solution deviated far from the optimum conditions.

    Original languageEnglish
    Pages (from-to)41-47
    Number of pages7
    JournalSolar Energy
    Volume64
    Issue number1-3
    DOIs
    Publication statusPublished - 1998 Sept

    ASJC Scopus subject areas

    • Renewable Energy, Sustainability and the Environment
    • General Materials Science

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