Proton-beam irradiation effect in TlH2PO4

S. H. Kim; K. W. Lee; J. W. Jang; Cheol Eui Lee; J. Y. Choi; K. S. Lee; J. Kim

doi:10.1103/PhysRevB.72.214107

Proton-beam irradiation effect in TlH2PO4

S. H. Kim, K. W. Lee, J. W. Jang, Cheol Eui Lee, J. Y. Choi, K. S. Lee, J. Kim

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

We have investigated the hydrogen ion beam irradiation effect on TlH2PO4 (TDP) showing an antiferroelectric phase transition and a ferroelastic phase transition. The polycrystalline sample was irradiated by 1MeV hydrogen ion beams to a dose of 1015ions cm2. The x-ray diffraction pattern shows a lattice elongation along the hydrogen bond direction. According to H1 rotating frame nuclear magnetic resonance measurements, the activation energy increased above the antiferroelectric phase transition after proton beam irradiation from 0.41to0.57eV, indicative of hampered proton motions. The temperature-dependent P31 high resolution nuclear magnetic resonance isotropic chemical shift indicated a displacive change in the PO4 tetrahedra, and the linewidth showed a broadening after the proton irradiation.

Original language	English
Article number	214107
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	72
Issue number	21
DOIs	https://doi.org/10.1103/PhysRevB.72.214107
Publication status	Published - 2005 Dec 1

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1103/PhysRevB.72.214107

Cite this

@article{501b6fd86b5e44faa2dbda602936795d,

title = "Proton-beam irradiation effect in TlH2PO4",

abstract = "We have investigated the hydrogen ion beam irradiation effect on TlH2PO4 (TDP) showing an antiferroelectric phase transition and a ferroelastic phase transition. The polycrystalline sample was irradiated by 1MeV hydrogen ion beams to a dose of 1015ions cm2. The x-ray diffraction pattern shows a lattice elongation along the hydrogen bond direction. According to H1 rotating frame nuclear magnetic resonance measurements, the activation energy increased above the antiferroelectric phase transition after proton beam irradiation from 0.41to0.57eV, indicative of hampered proton motions. The temperature-dependent P31 high resolution nuclear magnetic resonance isotropic chemical shift indicated a displacive change in the PO4 tetrahedra, and the linewidth showed a broadening after the proton irradiation.",

author = "Kim, {S. H.} and Lee, {K. W.} and Jang, {J. W.} and Lee, {Cheol Eui} and Choi, {J. Y.} and Lee, {K. S.} and J. Kim",

year = "2005",

month = dec,

day = "1",

doi = "10.1103/PhysRevB.72.214107",

language = "English",

volume = "72",

journal = "Physical Review B - Condensed Matter and Materials Physics",

issn = "1098-0121",

publisher = "American Institute of Physics",

number = "21",

}

TY - JOUR

T1 - Proton-beam irradiation effect in TlH2PO4

AU - Kim, S. H.

AU - Lee, K. W.

AU - Jang, J. W.

AU - Lee, Cheol Eui

AU - Choi, J. Y.

AU - Lee, K. S.

AU - Kim, J.

PY - 2005/12/1

Y1 - 2005/12/1

N2 - We have investigated the hydrogen ion beam irradiation effect on TlH2PO4 (TDP) showing an antiferroelectric phase transition and a ferroelastic phase transition. The polycrystalline sample was irradiated by 1MeV hydrogen ion beams to a dose of 1015ions cm2. The x-ray diffraction pattern shows a lattice elongation along the hydrogen bond direction. According to H1 rotating frame nuclear magnetic resonance measurements, the activation energy increased above the antiferroelectric phase transition after proton beam irradiation from 0.41to0.57eV, indicative of hampered proton motions. The temperature-dependent P31 high resolution nuclear magnetic resonance isotropic chemical shift indicated a displacive change in the PO4 tetrahedra, and the linewidth showed a broadening after the proton irradiation.

AB - We have investigated the hydrogen ion beam irradiation effect on TlH2PO4 (TDP) showing an antiferroelectric phase transition and a ferroelastic phase transition. The polycrystalline sample was irradiated by 1MeV hydrogen ion beams to a dose of 1015ions cm2. The x-ray diffraction pattern shows a lattice elongation along the hydrogen bond direction. According to H1 rotating frame nuclear magnetic resonance measurements, the activation energy increased above the antiferroelectric phase transition after proton beam irradiation from 0.41to0.57eV, indicative of hampered proton motions. The temperature-dependent P31 high resolution nuclear magnetic resonance isotropic chemical shift indicated a displacive change in the PO4 tetrahedra, and the linewidth showed a broadening after the proton irradiation.

UR - http://www.scopus.com/inward/record.url?scp=29744443926&partnerID=8YFLogxK

U2 - 10.1103/PhysRevB.72.214107

DO - 10.1103/PhysRevB.72.214107

M3 - Article

AN - SCOPUS:29744443926

SN - 1098-0121

VL - 72

JO - Physical Review B - Condensed Matter and Materials Physics

JF - Physical Review B - Condensed Matter and Materials Physics

IS - 21

M1 - 214107

ER -

Proton-beam irradiation effect in TlH2PO4

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this