Purification of Monomers Leads to High-Quality Lignin Macromonomers

S. A.R. Syed Azhar; Dong June Ahn

doi:10.1088/1757-899X/548/1/012021

Purification of Monomers Leads to High-Quality Lignin Macromonomers

S. A.R. Syed Azhar, Dong June Ahn

Research output: Contribution to journal › Conference article › peer-review

Abstract

Purification is critical in any chemical process. The removal of impurities will produce the product in better quality and high standard. In this study, a new type of monomer was prepared by condensation polymerization of alkali lignin (AL) and methacryloyl chloride (MAC). The effect of AL/MAC ratio and the purification of MAC were investigated. The physical and chemical properties of the product obtained which is lignin methacrylate (LMA) were characterized by Fourier Transformed Infrared spectroscopy (FT-IR) and Nuclear Magnetic Resonance (¹H-NMR). The result reveals that the purification was successfully removed the hydroxyl groups from the stabilizer in MAC and it is found that all the hydroxyl groups are coming from AL. The single interaction between and MAC has successfully enhanced the product obtain which does show no hydroxyl groups. The ¹H-NMR data also showed that the purification of MAC influences the outcome. The noise and impurities were eliminated after the purification of MAC, and more pure products were obtained. This new monomer (LMA) synthesis that can be further utilized for various applications.

Original language	English
Article number	012021
Journal	IOP Conference Series: Materials Science and Engineering
Volume	548
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/548/1/012021
Publication status	Published - 2019 Aug 27
Event	International Rubber Conference 2018, IRC 2018 - Kuala Lumpur, Malaysia Duration: 2018 Sept 4 → 2018 Sept 6

Bibliographical note

Funding Information:
This work was supported by the Majlis Amanah Rakyat (MARA) and National Research Foundation of Korea (NRF, 2017R1A2B3006770, 2017M3D1A1039421), KU-KIST Graduate School of Converging Science and Technology and a Korea University Grant.

Publisher Copyright:
© Published under licence by IOP Publishing Ltd.

ASJC Scopus subject areas

General Materials Science
General Engineering

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10.1088/1757-899X/548/1/012021

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title = "Purification of Monomers Leads to High-Quality Lignin Macromonomers",

abstract = "Purification is critical in any chemical process. The removal of impurities will produce the product in better quality and high standard. In this study, a new type of monomer was prepared by condensation polymerization of alkali lignin (AL) and methacryloyl chloride (MAC). The effect of AL/MAC ratio and the purification of MAC were investigated. The physical and chemical properties of the product obtained which is lignin methacrylate (LMA) were characterized by Fourier Transformed Infrared spectroscopy (FT-IR) and Nuclear Magnetic Resonance (1H-NMR). The result reveals that the purification was successfully removed the hydroxyl groups from the stabilizer in MAC and it is found that all the hydroxyl groups are coming from AL. The single interaction between and MAC has successfully enhanced the product obtain which does show no hydroxyl groups. The 1H-NMR data also showed that the purification of MAC influences the outcome. The noise and impurities were eliminated after the purification of MAC, and more pure products were obtained. This new monomer (LMA) synthesis that can be further utilized for various applications.",

author = "{Syed Azhar}, {S. A.R.} and Ahn, {Dong June}",

note = "Funding Information: This work was supported by the Majlis Amanah Rakyat (MARA) and National Research Foundation of Korea (NRF, 2017R1A2B3006770, 2017M3D1A1039421), KU-KIST Graduate School of Converging Science and Technology and a Korea University Grant. Publisher Copyright: {\textcopyright} Published under licence by IOP Publishing Ltd.; International Rubber Conference 2018, IRC 2018 ; Conference date: 04-09-2018 Through 06-09-2018",

year = "2019",

month = aug,

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doi = "10.1088/1757-899X/548/1/012021",

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T1 - Purification of Monomers Leads to High-Quality Lignin Macromonomers

AU - Syed Azhar, S. A.R.

AU - Ahn, Dong June

N1 - Funding Information: This work was supported by the Majlis Amanah Rakyat (MARA) and National Research Foundation of Korea (NRF, 2017R1A2B3006770, 2017M3D1A1039421), KU-KIST Graduate School of Converging Science and Technology and a Korea University Grant. Publisher Copyright: © Published under licence by IOP Publishing Ltd.

PY - 2019/8/27

Y1 - 2019/8/27

N2 - Purification is critical in any chemical process. The removal of impurities will produce the product in better quality and high standard. In this study, a new type of monomer was prepared by condensation polymerization of alkali lignin (AL) and methacryloyl chloride (MAC). The effect of AL/MAC ratio and the purification of MAC were investigated. The physical and chemical properties of the product obtained which is lignin methacrylate (LMA) were characterized by Fourier Transformed Infrared spectroscopy (FT-IR) and Nuclear Magnetic Resonance (1H-NMR). The result reveals that the purification was successfully removed the hydroxyl groups from the stabilizer in MAC and it is found that all the hydroxyl groups are coming from AL. The single interaction between and MAC has successfully enhanced the product obtain which does show no hydroxyl groups. The 1H-NMR data also showed that the purification of MAC influences the outcome. The noise and impurities were eliminated after the purification of MAC, and more pure products were obtained. This new monomer (LMA) synthesis that can be further utilized for various applications.

AB - Purification is critical in any chemical process. The removal of impurities will produce the product in better quality and high standard. In this study, a new type of monomer was prepared by condensation polymerization of alkali lignin (AL) and methacryloyl chloride (MAC). The effect of AL/MAC ratio and the purification of MAC were investigated. The physical and chemical properties of the product obtained which is lignin methacrylate (LMA) were characterized by Fourier Transformed Infrared spectroscopy (FT-IR) and Nuclear Magnetic Resonance (1H-NMR). The result reveals that the purification was successfully removed the hydroxyl groups from the stabilizer in MAC and it is found that all the hydroxyl groups are coming from AL. The single interaction between and MAC has successfully enhanced the product obtain which does show no hydroxyl groups. The 1H-NMR data also showed that the purification of MAC influences the outcome. The noise and impurities were eliminated after the purification of MAC, and more pure products were obtained. This new monomer (LMA) synthesis that can be further utilized for various applications.

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DO - 10.1088/1757-899X/548/1/012021

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SN - 1757-8981

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JO - IOP Conference Series: Materials Science and Engineering

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Y2 - 4 September 2018 through 6 September 2018

ER -

Purification of Monomers Leads to High-Quality Lignin Macromonomers

Abstract

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