Radical-radical reaction dynamics: The OH formation in the reaction of O(3P) with propargyl radical, C3H3

Hohjai Lee; Sun Kyu Joo; Lee Kyoung Kwon; Jong Ho Choi

doi:10.1063/1.1623176

Radical-radical reaction dynamics: The OH formation in the reaction of O(³P) with propargyl radical, C₃H₃

Hohjai Lee, Sun Kyu Joo, Lee Kyoung Kwon, Jong Ho Choi

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The first crossed-beam and ab initio studies of the reaction O(³P)+C₃H₃→¹c-C₃ H₂+OH is presented. The reaction dynamics is described in terms of two competing addition-complex mechanisms: a major short-lived dynamic complex in the high-N" regime and a minor long-lived statistical complex in the low-N" regime.

Original language	English
Pages (from-to)	9337-9340
Number of pages	4
Journal	Journal of Chemical Physics
Volume	119
Issue number	18
DOIs	https://doi.org/10.1063/1.1623176
Publication status	Published - 2003 Nov 8

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1623176

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abstract = "The first crossed-beam and ab initio studies of the reaction O(3P)+C3H3→1c-C3 H2+OH is presented. The reaction dynamics is described in terms of two competing addition-complex mechanisms: a major short-lived dynamic complex in the high-N{"} regime and a minor long-lived statistical complex in the low-N{"} regime.",

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AU - Kwon, Lee Kyoung

AU - Choi, Jong Ho

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AB - The first crossed-beam and ab initio studies of the reaction O(3P)+C3H3→1c-C3 H2+OH is presented. The reaction dynamics is described in terms of two competing addition-complex mechanisms: a major short-lived dynamic complex in the high-N" regime and a minor long-lived statistical complex in the low-N" regime.

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Radical-radical reaction dynamics: The OH formation in the reaction of O(³P) with propargyl radical, C₃H₃

Abstract

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