Reproducible formation of uniform CH3NH3PbI3-xClx mixed halide perovskite film by separation of the powder formation and spin-coating process

Dae Ho Song; Jin Hyuck Heo; Hye Ji Han; Myoung Sang You; Sang Hyuk Im

doi:10.1016/j.jpowsour.2016.02.010

Reproducible formation of uniform CH₃NH₃PbI_3-xCl_x mixed halide perovskite film by separation of the powder formation and spin-coating process

Dae Ho Song, Jin Hyuck Heo, Hye Ji Han, Myoung Sang You, Sang Hyuk Im

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

To deposit uniform CH₃NH₃PbI_3-xCl_x (MAPbI_3-xCl_x) mixed halide perovskite film reproducibly, we separated the conventional process to formation of MAPbI_3-xCl_x mixed halide perovskite powder by heat-treatment process and deposition of MAPbI_3-xCl_x mixed halide perovskite film by single step spin-coating. The deviation of power conversion efficiency of MAPbI_3-xCl_x mixed halide perovskite solar cells prepared by currently proposed method and conventional method was 13.75 ± 0.88% and 8.02 ± 1.65%, respectively, because more uniform MAPbI_3-xCl_x mixed halide perovskite film could be reproducibly formed by separating the formation process of mixed halide perovskite powder and the single step spin-coating process.

Original language	English
Pages (from-to)	130-136
Number of pages	7
Journal	Journal of Power Sources
Volume	310
DOIs	https://doi.org/10.1016/j.jpowsour.2016.02.010
Publication status	Published - 2016 Apr 1
Externally published	Yes

Bibliographical note

Funding Information:
D. Song and J. H. Heo contributed equally to this work. This study was supported by Mid-career Research Program (No. NRF-2013R1A2A2A01067999 ), Basic Science Research Program (No. 2014R1A5A1009799 ), and the Technology Development Program to Solve Climate Changes (No. 2015M1A2A2055631 ) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning .

Publisher Copyright:
© 2016 Elsevier B.V. All rights reserved.

Keywords

CHNHPbICl mixed halide perovskite
Perovskite powder
Perovskite solar cells
Reproducibility
Uniform film

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2016.02.010

Cite this

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title = "Reproducible formation of uniform CH3NH3PbI3-xClx mixed halide perovskite film by separation of the powder formation and spin-coating process",

abstract = "To deposit uniform CH3NH3PbI3-xClx (MAPbI3-xClx) mixed halide perovskite film reproducibly, we separated the conventional process to formation of MAPbI3-xClx mixed halide perovskite powder by heat-treatment process and deposition of MAPbI3-xClx mixed halide perovskite film by single step spin-coating. The deviation of power conversion efficiency of MAPbI3-xClx mixed halide perovskite solar cells prepared by currently proposed method and conventional method was 13.75 ± 0.88% and 8.02 ± 1.65%, respectively, because more uniform MAPbI3-xClx mixed halide perovskite film could be reproducibly formed by separating the formation process of mixed halide perovskite powder and the single step spin-coating process.",

keywords = "CHNHPbICl mixed halide perovskite, Perovskite powder, Perovskite solar cells, Reproducibility, Uniform film",

author = "Song, {Dae Ho} and Heo, {Jin Hyuck} and Han, {Hye Ji} and You, {Myoung Sang} and Im, {Sang Hyuk}",

note = "Funding Information: D. Song and J. H. Heo contributed equally to this work. This study was supported by Mid-career Research Program (No. NRF-2013R1A2A2A01067999 ), Basic Science Research Program (No. 2014R1A5A1009799 ), and the Technology Development Program to Solve Climate Changes (No. 2015M1A2A2055631 ) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning . Publisher Copyright: {\textcopyright} 2016 Elsevier B.V. All rights reserved.",

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AU - Han, Hye Ji

AU - You, Myoung Sang

AU - Im, Sang Hyuk

N1 - Funding Information: D. Song and J. H. Heo contributed equally to this work. This study was supported by Mid-career Research Program (No. NRF-2013R1A2A2A01067999 ), Basic Science Research Program (No. 2014R1A5A1009799 ), and the Technology Development Program to Solve Climate Changes (No. 2015M1A2A2055631 ) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning . Publisher Copyright: © 2016 Elsevier B.V. All rights reserved.

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N2 - To deposit uniform CH3NH3PbI3-xClx (MAPbI3-xClx) mixed halide perovskite film reproducibly, we separated the conventional process to formation of MAPbI3-xClx mixed halide perovskite powder by heat-treatment process and deposition of MAPbI3-xClx mixed halide perovskite film by single step spin-coating. The deviation of power conversion efficiency of MAPbI3-xClx mixed halide perovskite solar cells prepared by currently proposed method and conventional method was 13.75 ± 0.88% and 8.02 ± 1.65%, respectively, because more uniform MAPbI3-xClx mixed halide perovskite film could be reproducibly formed by separating the formation process of mixed halide perovskite powder and the single step spin-coating process.

AB - To deposit uniform CH3NH3PbI3-xClx (MAPbI3-xClx) mixed halide perovskite film reproducibly, we separated the conventional process to formation of MAPbI3-xClx mixed halide perovskite powder by heat-treatment process and deposition of MAPbI3-xClx mixed halide perovskite film by single step spin-coating. The deviation of power conversion efficiency of MAPbI3-xClx mixed halide perovskite solar cells prepared by currently proposed method and conventional method was 13.75 ± 0.88% and 8.02 ± 1.65%, respectively, because more uniform MAPbI3-xClx mixed halide perovskite film could be reproducibly formed by separating the formation process of mixed halide perovskite powder and the single step spin-coating process.

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