Reversible ammonia uptake at room temperature in a robust and tunable metal-organic framework

Jaechul Lee; Younggyu Seo; Dong Won Kang; Seungjae Park; Hyunyong Kim; Jaheon Kim; Kimoon Kim; Chang Seop Hong; Dae Woon Lim; Eunsung Lee

doi:10.1039/d2ra01270g

Reversible ammonia uptake at room temperature in a robust and tunable metal-organic framework

Jaechul Lee, Younggyu Seo, Dong Won Kang, Seungjae Park, Hyunyong Kim, Jaheon Kim, Kimoon Kim, Chang Seop Hong, Dae Woon Lim, Eunsung Lee

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Ammonia is useful for the production of fertilizers and chemicals for modern technology, but its high toxicity and corrosiveness are harmful to the environment and human health. Here, we report the recyclable and tunable ammonia adsorption using a robust imidazolium-based MOF (JCM-1) that uptakes 5.7 mmol g^-1of NH3 at 298 K reversibly without structural deformation. Furthermore, a simple substitution of NO3^-with Cl^-in a post-synthetic manner leads to an increase in the NH3 uptake capacity of JCM-1(Cl^-) up to 7.2

Original language	English
Pages (from-to)	7605-7611
Number of pages	7
Journal	RSC Advances
Volume	12
Issue number	13
DOIs	https://doi.org/10.1039/d2ra01270g
Publication status	Published - 2022 Mar 8

Bibliographical note

Funding Information:
This work was supported by Institute for Basic Science (IBS) [IBSR007-D1]. National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP: Ministry of Science, ICT and Future Planning) (No. NRF-2016H1A2A1908350 – Global PhD Fellowship Program). The X-ray crystallography analysis was performed at the Pohang Accelerator Laboratory (PLS-II BL2D SMC and 6D C&S Unist-PAL beamline). D.-W Lim acknowledges the support from the ACCEL program, Japan Science and Technology Agency (JST), JPMJAC1501. We thank Prof. S. S. Park for helpful discussion.

Publisher Copyright:
© 2022 Royal Society of Chemistry. All rights reserved.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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abstract = "Ammonia is useful for the production of fertilizers and chemicals for modern technology, but its high toxicity and corrosiveness are harmful to the environment and human health. Here, we report the recyclable and tunable ammonia adsorption using a robust imidazolium-based MOF (JCM-1) that uptakes 5.7 mmol g-1of NH3 at 298 K reversibly without structural deformation. Furthermore, a simple substitution of NO3-with Cl-in a post-synthetic manner leads to an increase in the NH3 uptake capacity of JCM-1(Cl-) up to 7.2",

author = "Jaechul Lee and Younggyu Seo and Kang, {Dong Won} and Seungjae Park and Hyunyong Kim and Jaheon Kim and Kimoon Kim and Hong, {Chang Seop} and Lim, {Dae Woon} and Eunsung Lee",

note = "Funding Information: This work was supported by Institute for Basic Science (IBS) [IBSR007-D1]. National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP: Ministry of Science, ICT and Future Planning) (No. NRF-2016H1A2A1908350 – Global PhD Fellowship Program). The X-ray crystallography analysis was performed at the Pohang Accelerator Laboratory (PLS-II BL2D SMC and 6D C&S Unist-PAL beamline). D.-W Lim acknowledges the support from the ACCEL program, Japan Science and Technology Agency (JST), JPMJAC1501. We thank Prof. S. S. Park for helpful discussion. Publisher Copyright: {\textcopyright} 2022 Royal Society of Chemistry. All rights reserved.",

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AU - Seo, Younggyu

AU - Kang, Dong Won

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AU - Kim, Hyunyong

AU - Kim, Jaheon

AU - Kim, Kimoon

AU - Hong, Chang Seop

AU - Lim, Dae Woon

AU - Lee, Eunsung

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AB - Ammonia is useful for the production of fertilizers and chemicals for modern technology, but its high toxicity and corrosiveness are harmful to the environment and human health. Here, we report the recyclable and tunable ammonia adsorption using a robust imidazolium-based MOF (JCM-1) that uptakes 5.7 mmol g-1of NH3 at 298 K reversibly without structural deformation. Furthermore, a simple substitution of NO3-with Cl-in a post-synthetic manner leads to an increase in the NH3 uptake capacity of JCM-1(Cl-) up to 7.2

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Reversible ammonia uptake at room temperature in a robust and tunable metal-organic framework

Abstract

Bibliographical note

ASJC Scopus subject areas

UN SDGs

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