Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged MII (M = Mn, Ni) coordination polymers

Kwang Soo Lim, Jeong Hwa Song, Dong Won Kang, Minjung Kang, Sunhwi Eom, Eui Kwan Koh, Chang Seop Hong

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

MII (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations during the hydration-dehydration process. Moreover, the magnetic nature changes from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.

Original languageEnglish
Pages (from-to)845-851
Number of pages7
JournalDalton Transactions
Volume47
Issue number3
DOIs
Publication statusPublished - 2018

Bibliographical note

Funding Information:
This work was supported by a Korea CCS R&D Center (KCRC) grant funded by the Korean government (the Ministry of Science, ICT, & Future Planning (MSIP)) (NRF-2012-0008901), by the Basic Science Research Program (NRF-2015R1A2A1A10055658), and by the Priority Research Centers Program (NRF2010-0020209).

Publisher Copyright:
© The Royal Society of Chemistry 2018.

ASJC Scopus subject areas

  • Inorganic Chemistry

Fingerprint

Dive into the research topics of 'Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged MII (M = Mn, Ni) coordination polymers'. Together they form a unique fingerprint.

Cite this