Reversible transformation between methylene and methylidyne-hydride moieties on the Ru10C2 framework

Kwangyeol Lee; Scott R. Wilson; John R. Shapley

doi:10.1021/om971120r

Reversible transformation between methylene and methylidyne-hydride moieties on the Ru₁₀C₂ framework

Kwangyeol Lee, Scott R. Wilson, John R. Shapley

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Oxidative substitution of [Ru₁₀C₂(CO)₂₂-(NBD)]^2- with ferrocenium ion and diazomethane forms a methylene compound, Ru₁₀C₂(CO)₂₂(NBD)(μ-CH₂), in which the methylene ligand symmetrically bridges two adjacent apical ruthenium centers in the edge-fused bioctahedral Ru₁₀C₂ framework. A methylidyne tautomer, Ru₁₀C₂(CO)₂₂(NBD)(CH)(H), is formed reversibly at 80°C.

Original language	English
Pages (from-to)	4113-4116
Number of pages	4
Journal	Organometallics
Volume	17
Issue number	18
DOIs	https://doi.org/10.1021/om971120r
Publication status	Published - 1998 Aug 31
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Reversible transformation between methylene and methylidyne-hydride moieties on the Ru10C2 framework",

abstract = "Oxidative substitution of [Ru10C2(CO)22-(NBD)]2- with ferrocenium ion and diazomethane forms a methylene compound, Ru10C2(CO)22(NBD)(μ-CH2), in which the methylene ligand symmetrically bridges two adjacent apical ruthenium centers in the edge-fused bioctahedral Ru10C2 framework. A methylidyne tautomer, Ru10C2(CO)22(NBD)(CH)(H), is formed reversibly at 80°C.",

author = "Kwangyeol Lee and Wilson, {Scott R.} and Shapley, {John R.}",

year = "1998",

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doi = "10.1021/om971120r",

language = "English",

volume = "17",

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journal = "Organometallics",

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T1 - Reversible transformation between methylene and methylidyne-hydride moieties on the Ru10C2 framework

AU - Lee, Kwangyeol

AU - Wilson, Scott R.

AU - Shapley, John R.

PY - 1998/8/31

Y1 - 1998/8/31

N2 - Oxidative substitution of [Ru10C2(CO)22-(NBD)]2- with ferrocenium ion and diazomethane forms a methylene compound, Ru10C2(CO)22(NBD)(μ-CH2), in which the methylene ligand symmetrically bridges two adjacent apical ruthenium centers in the edge-fused bioctahedral Ru10C2 framework. A methylidyne tautomer, Ru10C2(CO)22(NBD)(CH)(H), is formed reversibly at 80°C.

AB - Oxidative substitution of [Ru10C2(CO)22-(NBD)]2- with ferrocenium ion and diazomethane forms a methylene compound, Ru10C2(CO)22(NBD)(μ-CH2), in which the methylene ligand symmetrically bridges two adjacent apical ruthenium centers in the edge-fused bioctahedral Ru10C2 framework. A methylidyne tautomer, Ru10C2(CO)22(NBD)(CH)(H), is formed reversibly at 80°C.

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U2 - 10.1021/om971120r

DO - 10.1021/om971120r

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AN - SCOPUS:0000702203

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JO - Organometallics

JF - Organometallics

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ER -

Reversible transformation between methylene and methylidyne-hydride moieties on the Ru₁₀C₂ framework

Abstract

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