Abstract
Oxidative substitution of [Ru10C2(CO)22-(NBD)]2- with ferrocenium ion and diazomethane forms a methylene compound, Ru10C2(CO)22(NBD)(μ-CH2), in which the methylene ligand symmetrically bridges two adjacent apical ruthenium centers in the edge-fused bioctahedral Ru10C2 framework. A methylidyne tautomer, Ru10C2(CO)22(NBD)(CH)(H), is formed reversibly at 80°C.
Original language | English |
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Pages (from-to) | 4113-4116 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 17 |
Issue number | 18 |
DOIs | |
Publication status | Published - 1998 Aug 31 |
Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry