Abstract
X-ray structural analysis shows that {[Cu2(CTA) (H2O)] · 5 H2O}n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm-1) and antiferromagnetic (J = -2.5 cm-1) interactions.
Original language | English |
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Pages (from-to) | 527-530 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 10 |
Issue number | 5 |
DOIs | |
Publication status | Published - 2007 May |
Keywords
- Alternate ferro- and antiferromagnetic interactions
- Inclusion chemistry
- Metal-organic frameworks
- X-ray structural characterization
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry