Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Ambarish Ray, Chang Seop Hong, Swastik Mondal, Monika Mukherjee, Mahammad Ali

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    X-ray structural analysis shows that {[Cu2(CTA) (H2O)] · 5 H2O}n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm-1) and antiferromagnetic (J = -2.5 cm-1) interactions.

    Original languageEnglish
    Pages (from-to)527-530
    Number of pages4
    JournalInorganic Chemistry Communications
    Volume10
    Issue number5
    DOIs
    Publication statusPublished - 2007 May

    Bibliographical note

    Funding Information:
    M. A. gratefully acknowledges the financial assistances from the UGC (Ref. No. F.12-22/2003(SR) and DST (Ref. No. SR/SI/IC-19/2002), New Delhi.

    Keywords

    • Alternate ferro- and antiferromagnetic interactions
    • Inclusion chemistry
    • Metal-organic frameworks
    • X-ray structural characterization

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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