Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Ambarish Ray; Chang Seop Hong; Swastik Mondal; Monika Mukherjee; Mahammad Ali

doi:10.1016/j.inoche.2006.12.013

Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Ambarish Ray, Chang Seop Hong, Swastik Mondal, Monika Mukherjee, Mahammad Ali

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

X-ray structural analysis shows that {[Cu₂(CTA) (H₂O)] · 5 H₂O}_n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm^-1) and antiferromagnetic (J = -2.5 cm^-1) interactions.

Original language	English
Pages (from-to)	527-530
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	5
DOIs	https://doi.org/10.1016/j.inoche.2006.12.013
Publication status	Published - 2007 May

Keywords

Alternate ferro- and antiferromagnetic interactions
Inclusion chemistry
Metal-organic frameworks
X-ray structural characterization

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2006.12.013

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Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions. / Ray, Ambarish; Hong, Chang Seop; Mondal, Swastik et al.
In: Inorganic Chemistry Communications, Vol. 10, No. 5, 05.2007, p. 527-530.

Research output: Contribution to journal › Article › peer-review

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title = "Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions",

abstract = "X-ray structural analysis shows that {[Cu2(CTA) (H2O)] · 5 H2O}n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm-1) and antiferromagnetic (J = -2.5 cm-1) interactions.",

keywords = "Alternate ferro- and antiferromagnetic interactions, Inclusion chemistry, Metal-organic frameworks, X-ray structural characterization",

author = "Ambarish Ray and Hong, {Chang Seop} and Swastik Mondal and Monika Mukherjee and Mahammad Ali",

note = "Funding Information: M. A. gratefully acknowledges the financial assistances from the UGC (Ref. No. F.12-22/2003(SR) and DST (Ref. No. SR/SI/IC-19/2002), New Delhi. ",

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AU - Mondal, Swastik

AU - Mukherjee, Monika

AU - Ali, Mahammad

N1 - Funding Information: M. A. gratefully acknowledges the financial assistances from the UGC (Ref. No. F.12-22/2003(SR) and DST (Ref. No. SR/SI/IC-19/2002), New Delhi.

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KW - Alternate ferro- and antiferromagnetic interactions

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Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Abstract

Keywords

ASJC Scopus subject areas

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