Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Ambarish Ray; Chang Seop Hong; Swastik Mondal; Monika Mukherjee; Mahammad Ali

doi:10.1016/j.inoche.2006.12.013

Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Ambarish Ray
, Chang Seop Hong
, Swastik Mondal
, Monika Mukherjee
, Mahammad Ali^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

X-ray structural analysis shows that {[Cu₂(CTA) (H₂O)] · 5 H₂O}_n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm^-1) and antiferromagnetic (J = -2.5 cm^-1) interactions.

Original language	English
Pages (from-to)	527-530
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	5
DOIs	https://doi.org/10.1016/j.inoche.2006.12.013
Publication status	Published - 2007 May

Bibliographical note

Funding Information:
M. A. gratefully acknowledges the financial assistances from the UGC (Ref. No. F.12-22/2003(SR) and DST (Ref. No. SR/SI/IC-19/2002), New Delhi.

Keywords

Alternate ferro- and antiferromagnetic interactions
Inclusion chemistry
Metal-organic frameworks
X-ray structural characterization

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2006.12.013

Cite this

Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions. / Ray, Ambarish; Hong, Chang Seop; Mondal, Swastik et al.
In: Inorganic Chemistry Communications, Vol. 10, No. 5, 05.2007, p. 527-530.

Research output: Contribution to journal › Article › peer-review

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title = "Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions",

abstract = "X-ray structural analysis shows that \{[Cu2(CTA) (H2O)] · 5 H2O\}n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm-1) and antiferromagnetic (J = -2.5 cm-1) interactions.",

keywords = "Alternate ferro- and antiferromagnetic interactions, Inclusion chemistry, Metal-organic frameworks, X-ray structural characterization",

author = "Ambarish Ray and Hong, \{Chang Seop\} and Swastik Mondal and Monika Mukherjee and Mahammad Ali",

note = "Funding Information: M. A. gratefully acknowledges the financial assistances from the UGC (Ref. No. F.12-22/2003(SR) and DST (Ref. No. SR/SI/IC-19/2002), New Delhi. ",

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AU - Ray, Ambarish

AU - Hong, Chang Seop

AU - Mondal, Swastik

AU - Mukherjee, Monika

AU - Ali, Mahammad

N1 - Funding Information: M. A. gratefully acknowledges the financial assistances from the UGC (Ref. No. F.12-22/2003(SR) and DST (Ref. No. SR/SI/IC-19/2002), New Delhi.

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N2 - X-ray structural analysis shows that {[Cu2(CTA) (H2O)] · 5 H2O}n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm-1) and antiferromagnetic (J = -2.5 cm-1) interactions.

AB - X-ray structural analysis shows that {[Cu2(CTA) (H2O)] · 5 H2O}n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm-1) and antiferromagnetic (J = -2.5 cm-1) interactions.

KW - Alternate ferro- and antiferromagnetic interactions

KW - Inclusion chemistry

KW - Metal-organic frameworks

KW - X-ray structural characterization

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DO - 10.1016/j.inoche.2006.12.013

M3 - Article

AN - SCOPUS:34047249060

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VL - 10

SP - 527

EP - 530

JO - Inorganic Chemistry Communications

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IS - 5

ER -

Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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