Selective deoxygenation of amine N-oxides using borohydride exchange resin-copper sulfate in methanol

Tae Bo Sim; Jin Hee Ahn; Nung Min Yoon

doi:10.1055/s-1996-4221

Selective deoxygenation of amine N-oxides using borohydride exchange resin-copper sulfate in methanol

Tae Bo Sim, Jin Hee Ahn, Nung Min Yoon

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Borohydride exchange resin-copper sulfate in methanol readily deoxygenates quantitatively both tertiary amine N-oxides and heteroaromatic N-oxides at room temperature or under reflux. It tolerates many functional groups such as carbon-carbon double bond, chloride, epoxide, ester, amide, nitrile, sulfoxide, sulfone, and aliphatic disulfide moieties.

Original language	English
Pages (from-to)	324-326
Number of pages	3
Journal	Synthesis
Issue number	3
DOIs	https://doi.org/10.1055/s-1996-4221
Publication status	Published - 1996
Externally published	Yes

Keywords

borohydride exchange resin
copper catalyst
heteroaromatic N-oxides
selective deoxygenation
tertiary amine N-oxides

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-1996-4221

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abstract = "Borohydride exchange resin-copper sulfate in methanol readily deoxygenates quantitatively both tertiary amine N-oxides and heteroaromatic N-oxides at room temperature or under reflux. It tolerates many functional groups such as carbon-carbon double bond, chloride, epoxide, ester, amide, nitrile, sulfoxide, sulfone, and aliphatic disulfide moieties.",

keywords = "borohydride exchange resin, copper catalyst, heteroaromatic N-oxides, selective deoxygenation, tertiary amine N-oxides",

author = "Sim, {Tae Bo} and Ahn, {Jin Hee} and Yoon, {Nung Min}",

year = "1996",

doi = "10.1055/s-1996-4221",

language = "English",

pages = "324--326",

journal = "Synthesis",

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T1 - Selective deoxygenation of amine N-oxides using borohydride exchange resin-copper sulfate in methanol

AU - Sim, Tae Bo

AU - Ahn, Jin Hee

AU - Yoon, Nung Min

PY - 1996

Y1 - 1996

N2 - Borohydride exchange resin-copper sulfate in methanol readily deoxygenates quantitatively both tertiary amine N-oxides and heteroaromatic N-oxides at room temperature or under reflux. It tolerates many functional groups such as carbon-carbon double bond, chloride, epoxide, ester, amide, nitrile, sulfoxide, sulfone, and aliphatic disulfide moieties.

AB - Borohydride exchange resin-copper sulfate in methanol readily deoxygenates quantitatively both tertiary amine N-oxides and heteroaromatic N-oxides at room temperature or under reflux. It tolerates many functional groups such as carbon-carbon double bond, chloride, epoxide, ester, amide, nitrile, sulfoxide, sulfone, and aliphatic disulfide moieties.

KW - borohydride exchange resin

KW - copper catalyst

KW - heteroaromatic N-oxides

KW - selective deoxygenation

KW - tertiary amine N-oxides

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DO - 10.1055/s-1996-4221

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JO - Synthesis

JF - Synthesis

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ER -

Selective deoxygenation of amine N-oxides using borohydride exchange resin-copper sulfate in methanol

Abstract

Keywords

ASJC Scopus subject areas

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