Selective Sorption of Alkali-Metal Cations by Carboxylic Acid Resins Containing Acyclic or Cyclic Polyether Units

Takashi Hayashita; Mi Ja Goo; Jong Chan Lee; Jong Seung Kim; Jan Krzykawski; Richard A. Bartsch

doi:10.1021/ac00220a006

Selective Sorption of Alkali-Metal Cations by Carboxylic Acid Resins Containing Acyclic or Cyclic Polyether Units

Takashi Hayashita, Mi Ja Goo, Jong Chan Lee, Jong Seung Kim, Jan Krzykawski, Richard A. Bartsch

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Novel ion-exchange resins have been prepared by condensation polymerization with formaldehyde In formic acid of three polyether carboxylic acids which possess two benzo group substituents. The selectivities and efficiencies of competitive alkali-metal cation sorption from aqueous solutions by these polyether carboxylic acid resins are strongly influenced by (1) the pH of the aqueous solution, (2) the acyclic or cyclic nature of the polyether unit, and (3) the conformational positioning of the carboxylic acid group In the resins derived from cyclic polyether (crown ether) compounds. Good sorption selectivity for Na⁺ was observed for dibenzo-16-crown-5 resin 3 in which the pendant carboxylic acid group is oriented over the polyether cavity. Resin 3 was utilized as a stationary phase for selective column concentration of Na⁺ from dilute aqueous solution.

Original language	English
Pages (from-to)	2283-2287
Number of pages	5
Journal	Analytical chemistry
Volume	62
Issue number	21
DOIs	https://doi.org/10.1021/ac00220a006
Publication status	Published - 1990 Jan 15
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry

Access to Document

10.1021/ac00220a006

Cite this

@article{dfacffd3f62548328fa9adbd1002e212,

title = "Selective Sorption of Alkali-Metal Cations by Carboxylic Acid Resins Containing Acyclic or Cyclic Polyether Units",

abstract = "Novel ion-exchange resins have been prepared by condensation polymerization with formaldehyde In formic acid of three polyether carboxylic acids which possess two benzo group substituents. The selectivities and efficiencies of competitive alkali-metal cation sorption from aqueous solutions by these polyether carboxylic acid resins are strongly influenced by (1) the pH of the aqueous solution, (2) the acyclic or cyclic nature of the polyether unit, and (3) the conformational positioning of the carboxylic acid group In the resins derived from cyclic polyether (crown ether) compounds. Good sorption selectivity for Na+ was observed for dibenzo-16-crown-5 resin 3 in which the pendant carboxylic acid group is oriented over the polyether cavity. Resin 3 was utilized as a stationary phase for selective column concentration of Na+ from dilute aqueous solution.",

author = "Takashi Hayashita and Goo, {Mi Ja} and Lee, {Jong Chan} and Kim, {Jong Seung} and Jan Krzykawski and Bartsch, {Richard A.}",

year = "1990",

month = jan,

day = "15",

doi = "10.1021/ac00220a006",

language = "English",

volume = "62",

pages = "2283--2287",

journal = "Analytical Chemistry",

issn = "0003-2700",

number = "21",

}

TY - JOUR

T1 - Selective Sorption of Alkali-Metal Cations by Carboxylic Acid Resins Containing Acyclic or Cyclic Polyether Units

AU - Hayashita, Takashi

AU - Goo, Mi Ja

AU - Lee, Jong Chan

AU - Kim, Jong Seung

AU - Krzykawski, Jan

AU - Bartsch, Richard A.

PY - 1990/1/15

Y1 - 1990/1/15

N2 - Novel ion-exchange resins have been prepared by condensation polymerization with formaldehyde In formic acid of three polyether carboxylic acids which possess two benzo group substituents. The selectivities and efficiencies of competitive alkali-metal cation sorption from aqueous solutions by these polyether carboxylic acid resins are strongly influenced by (1) the pH of the aqueous solution, (2) the acyclic or cyclic nature of the polyether unit, and (3) the conformational positioning of the carboxylic acid group In the resins derived from cyclic polyether (crown ether) compounds. Good sorption selectivity for Na+ was observed for dibenzo-16-crown-5 resin 3 in which the pendant carboxylic acid group is oriented over the polyether cavity. Resin 3 was utilized as a stationary phase for selective column concentration of Na+ from dilute aqueous solution.

AB - Novel ion-exchange resins have been prepared by condensation polymerization with formaldehyde In formic acid of three polyether carboxylic acids which possess two benzo group substituents. The selectivities and efficiencies of competitive alkali-metal cation sorption from aqueous solutions by these polyether carboxylic acid resins are strongly influenced by (1) the pH of the aqueous solution, (2) the acyclic or cyclic nature of the polyether unit, and (3) the conformational positioning of the carboxylic acid group In the resins derived from cyclic polyether (crown ether) compounds. Good sorption selectivity for Na+ was observed for dibenzo-16-crown-5 resin 3 in which the pendant carboxylic acid group is oriented over the polyether cavity. Resin 3 was utilized as a stationary phase for selective column concentration of Na+ from dilute aqueous solution.

UR - http://www.scopus.com/inward/record.url?scp=0025000159&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0025000159&partnerID=8YFLogxK

U2 - 10.1021/ac00220a006

DO - 10.1021/ac00220a006

M3 - Article

AN - SCOPUS:0025000159

SN - 0003-2700

VL - 62

SP - 2283

EP - 2287

JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 21

ER -

Selective Sorption of Alkali-Metal Cations by Carboxylic Acid Resins Containing Acyclic or Cyclic Polyether Units

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this