Shaping of a Metal-Organic Framework-Polymer Composite and Its CO2Adsorption Performances from Humid Indoor Air

Jinkyoung Park; Yun Seok Chae; Dong Won Kang; Minjung Kang; Jong Hyeak Choe; Saemi Kim; Jee Yeon Kim; Yong Won Jeong; Chang Seop Hong

doi:10.1021/acsami.1c06089

Shaping of a Metal-Organic Framework-Polymer Composite and Its CO₂Adsorption Performances from Humid Indoor Air

Jinkyoung Park, Yun Seok Chae, Dong Won Kang, Minjung Kang, Jong Hyeak Choe, Saemi Kim, Jee Yeon Kim, Yong Won Jeong, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Diamine-functionalized metal-organic frameworks (MOFs) are known as desirable adsorbents that can capture CO2 even at low pressures, but the humidity instability of bare MOF powders as well as their shaping have not yet adequately addressed for practical applications. Herein, we report an effective synthetic strategy for fabricating millimeter-sized MOF/poly(vinylidene fluoride) (PVDF) composite beads with different amounts of PVDF binders (30, 40, and 50 wt %) via a phase inversion method, followed by the postfunctionalization of 1-ethylpropane-1,3-diamine (epn). Compared with the pristine MOF powder, the diamine-grafted bead, epn-MOF/PVDF40, upon mixing with 40% binder polymers, exhibited a superior long-term performance without structural collapse for up to 1 month. The existence of the hydrophobic PVDF polymer in the composite material is responsible for such durability. This work provides a promising preparative route toward developing stable and shaped MOFs for the removal of indoor CO2.

Original language	English
Pages (from-to)	25421-25427
Number of pages	7
Journal	ACS Applied Materials and Interfaces
Volume	13
Issue number	21
DOIs	https://doi.org/10.1021/acsami.1c06089
Publication status	Published - 2021 Jun 2

Bibliographical note

Funding Information:
This work was supported by Samsung Research, Samsung Electronics Co., Ltd., the Basic Science Research Program (NRF-2018R1A2A1A05079297), and the Priority Research Centers Program (NRF-2019R1A6A1A11044070). We thank the Institute for Basic Science (IBS) Center for Molecular Spectroscopy and Dynamics (IBS-R023-D1) for providing NMR spectrometry and professional technical support.

Publisher Copyright:
© 2021 American Chemical Society. All rights reserved.

Keywords

MOF shaping
composite materials
diamine functionalization
indoor air capture
metal-organic framework

ASJC Scopus subject areas

Materials Science(all)

Access to Document

10.1021/acsami.1c06089

Cite this

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title = "Shaping of a Metal-Organic Framework-Polymer Composite and Its CO2Adsorption Performances from Humid Indoor Air",

abstract = "Diamine-functionalized metal-organic frameworks (MOFs) are known as desirable adsorbents that can capture CO2 even at low pressures, but the humidity instability of bare MOF powders as well as their shaping have not yet adequately addressed for practical applications. Herein, we report an effective synthetic strategy for fabricating millimeter-sized MOF/poly(vinylidene fluoride) (PVDF) composite beads with different amounts of PVDF binders (30, 40, and 50 wt %) via a phase inversion method, followed by the postfunctionalization of 1-ethylpropane-1,3-diamine (epn). Compared with the pristine MOF powder, the diamine-grafted bead, epn-MOF/PVDF40, upon mixing with 40% binder polymers, exhibited a superior long-term performance without structural collapse for up to 1 month. The existence of the hydrophobic PVDF polymer in the composite material is responsible for such durability. This work provides a promising preparative route toward developing stable and shaped MOFs for the removal of indoor CO2.",

keywords = "MOF shaping, composite materials, diamine functionalization, indoor air capture, metal-organic framework",

author = "Jinkyoung Park and Chae, {Yun Seok} and Kang, {Dong Won} and Minjung Kang and Choe, {Jong Hyeak} and Saemi Kim and Kim, {Jee Yeon} and Jeong, {Yong Won} and Hong, {Chang Seop}",

note = "Funding Information: This work was supported by Samsung Research, Samsung Electronics Co., Ltd., the Basic Science Research Program (NRF-2018R1A2A1A05079297), and the Priority Research Centers Program (NRF-2019R1A6A1A11044070). We thank the Institute for Basic Science (IBS) Center for Molecular Spectroscopy and Dynamics (IBS-R023-D1) for providing NMR spectrometry and professional technical support. Publisher Copyright: {\textcopyright} 2021 American Chemical Society. All rights reserved.",

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AU - Chae, Yun Seok

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AU - Kang, Minjung

AU - Choe, Jong Hyeak

AU - Kim, Saemi

AU - Kim, Jee Yeon

AU - Jeong, Yong Won

AU - Hong, Chang Seop

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PY - 2021/6/2

Y1 - 2021/6/2

N2 - Diamine-functionalized metal-organic frameworks (MOFs) are known as desirable adsorbents that can capture CO2 even at low pressures, but the humidity instability of bare MOF powders as well as their shaping have not yet adequately addressed for practical applications. Herein, we report an effective synthetic strategy for fabricating millimeter-sized MOF/poly(vinylidene fluoride) (PVDF) composite beads with different amounts of PVDF binders (30, 40, and 50 wt %) via a phase inversion method, followed by the postfunctionalization of 1-ethylpropane-1,3-diamine (epn). Compared with the pristine MOF powder, the diamine-grafted bead, epn-MOF/PVDF40, upon mixing with 40% binder polymers, exhibited a superior long-term performance without structural collapse for up to 1 month. The existence of the hydrophobic PVDF polymer in the composite material is responsible for such durability. This work provides a promising preparative route toward developing stable and shaped MOFs for the removal of indoor CO2.

AB - Diamine-functionalized metal-organic frameworks (MOFs) are known as desirable adsorbents that can capture CO2 even at low pressures, but the humidity instability of bare MOF powders as well as their shaping have not yet adequately addressed for practical applications. Herein, we report an effective synthetic strategy for fabricating millimeter-sized MOF/poly(vinylidene fluoride) (PVDF) composite beads with different amounts of PVDF binders (30, 40, and 50 wt %) via a phase inversion method, followed by the postfunctionalization of 1-ethylpropane-1,3-diamine (epn). Compared with the pristine MOF powder, the diamine-grafted bead, epn-MOF/PVDF40, upon mixing with 40% binder polymers, exhibited a superior long-term performance without structural collapse for up to 1 month. The existence of the hydrophobic PVDF polymer in the composite material is responsible for such durability. This work provides a promising preparative route toward developing stable and shaped MOFs for the removal of indoor CO2.

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