Size-controlled crystalline nanocubic coordination polymer particles from chiral Zn-salen and Co(II) have been obtained. PXRD patterns show that these particles have an identical unit cell regardless of a wide range of size distributions. Furthermore, cubic particles with epitaxial layers have been obtained with a simple manipulation during the synthesis.
Bibliographical noteFunding Information:
The authors acknowledge financial support from the National Research Foundation Program (No. 20100011942 ) and Priority Research Centers Program (NRF 2011-0018396 ) through the NRF of Korea funded by the Ministry of Education, Science and Technology (MEST).
- Coordination polymer particle
- Gas sorption
- Metal-organic frameworks
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry