Solution-Based Deep Prelithiation for Lithium-Ion Capacitors with High Energy Density

Seungyun Jeon, Sehee lm, Inyeong Kang, Dongki Shin, Seung Ho Yu, Minah Lee, Jihyun Hong

Research output: Contribution to journalArticlepeer-review

Abstract

Lithium-ion capacitors (LICs) exhibit superior power density and cyclability compared to lithium-ion batteries. However, the low initial Coulombic efficiency (ICE) of amorphous carbon anodes (e.g., hard carbon (HC) and soft carbon (SC)) limits the energy density of LICs by underutilizing cathode capacity. Here, a solution-based deep prelithiation strategy for carbon anodes is applied using a contact-ion pair dominant solution, offering high energy density based on a systematic electrode balancing based on the cathode capacity increased beyond the original theoretical limit. Increasing the anode ICE to 150% over 100%, the activated carbon (AC) capacity is doubled by activating Li+ cation storage, which unleashes rocking-chair LIC operation alongside the dual-ion-storage mechanism. The increased AC capacity results in an energy density of 106.6 Wh kg−1AC+SC, equivalent to 281% of that of LICs without prelithiation. Moreover, this process lowers the cathode-anode mass ratio, reducing the cell thickness by 67% without compromising the cell capacity. This solution-based deep chemical prelithiation promises high-energy LICs based on transition metal-free, earth-abundant active materials to meet the practical demands of power-intensive applications.

Original languageEnglish
JournalSmall
DOIs
Publication statusAccepted/In press - 2024

Bibliographical note

Publisher Copyright:
© 2024 The Authors. Small published by Wiley-VCH GmbH.

Keywords

  • contact-ion pairs
  • deep prelithiation
  • dual-ion-storage
  • electrode balancing
  • lithium-ion capacitors
  • rocking-chair mechanism

ASJC Scopus subject areas

  • Biotechnology
  • General Chemistry
  • Biomaterials
  • General Materials Science
  • Engineering (miscellaneous)

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