Solvent intermolecular polarizability response in solvation

Sungnam Park; Bret N. Flanders; Xiaoming Shang; Robert A. Westervelt; Jeongho Kim; Norbert F. Scherer

doi:10.1063/1.1555804

Solvent intermolecular polarizability response in solvation

Sungnam Park, Bret N. Flanders, Xiaoming Shang, Robert A. Westervelt, Jeongho Kim, Norbert F. Scherer

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Polarizability response spectroscopy (PORS) measurements were performed at a series of C153 concentrations in a variety of solvents. In contrast to the PORS signals from the neat solvents, it was found that the PORS signals from the solutions are primarily negative in amplitude with a long decay component. The long-time decay of the negative signal was fit with an exponential function. While the magnitude of the negative signals increased with concentration, the decay time only depended on the solvent.

Original language	English
Pages (from-to)	3917-3920
Number of pages	4
Journal	Journal of Chemical Physics
Volume	118
Issue number	9
DOIs	https://doi.org/10.1063/1.1555804
Publication status	Published - 2003 Mar 1
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1555804

Cite this

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AU - Park, Sungnam

AU - Flanders, Bret N.

AU - Shang, Xiaoming

AU - Westervelt, Robert A.

AU - Kim, Jeongho

AU - Scherer, Norbert F.

PY - 2003/3/1

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AB - Polarizability response spectroscopy (PORS) measurements were performed at a series of C153 concentrations in a variety of solvents. In contrast to the PORS signals from the neat solvents, it was found that the PORS signals from the solutions are primarily negative in amplitude with a long decay component. The long-time decay of the negative signal was fit with an exponential function. While the magnitude of the negative signals increased with concentration, the decay time only depended on the solvent.

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DO - 10.1063/1.1555804

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Solvent intermolecular polarizability response in solvation

Abstract

ASJC Scopus subject areas

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