TY - JOUR
T1 - Solvent recovery in solvent deasphalting process for economical vacuum residue upgrading
AU - Ahn, Seonju
AU - Shin, Sangcheol
AU - Im, Soo Ik
AU - Lee, Ki Bong
AU - Nho, Nam Sun
N1 - Funding Information:
This research was supported by grants from the Korea Institute of Energy Research, the R&D Convergence Program of the Korea government Ministry of Science, ICT and Future Planning (MSIP) and the Korea Research Council for Industrial Science and Technology (B551179-12-07-00), and the Human Resources Development Program (20134010200600) of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) funded by the Ministry of Trade, Industry and Energy of Korea. We also would like to acknowledge the financial support from the R&D Convergence Program of MSIP and National Research Council of Science & Technology (NST) of Republic of Korea (CRC-14-1-KRICT).
Publisher Copyright:
© 2016, Korean Institute of Chemical Engineers, Seoul, Korea.
Copyright:
Copyright 2016 Elsevier B.V., All rights reserved.
PY - 2016/1/1
Y1 - 2016/1/1
N2 - The solvent deasphalting (SDA) process is a heavy oil upgrading process and used to separate asphaltene, the heaviest and most polar fraction of vacuum residue (VR) of heavy oil, by using density differences, to obtain deasphalted oil (DAO). The SDA process consists of two main stages: asphaltene separation and solvent recovery. Solvent recovery is a key procedure for determining the operating cost of the SDA process, because it uses a considerable amount of costly solvent, the recovery of which consumes huge amounts of energy. In this study, the SDA process was numerically simulated by using three different solvents, propane, n-butane, and isobutane, to examine their effect on the DAO extraction and the effect of the operating temperature and pressure on solvent recovery. The process was designed to contain one extractor, two flash drums, and two steam strippers. The VR was characterized by identifying 15 pseudo-components based on the boiling point distribution, obtained by performing a SIMDIS analysis, and the API gravity of the components. When n-butane was used, the yield of DAO was higher than in the other cases, whereas isobutane showed a similar extraction performance as propane. Solvent recovery was found to increase with temperature and decrease with pressure for all the solvents that were tested and the best results were obtained for propane.
AB - The solvent deasphalting (SDA) process is a heavy oil upgrading process and used to separate asphaltene, the heaviest and most polar fraction of vacuum residue (VR) of heavy oil, by using density differences, to obtain deasphalted oil (DAO). The SDA process consists of two main stages: asphaltene separation and solvent recovery. Solvent recovery is a key procedure for determining the operating cost of the SDA process, because it uses a considerable amount of costly solvent, the recovery of which consumes huge amounts of energy. In this study, the SDA process was numerically simulated by using three different solvents, propane, n-butane, and isobutane, to examine their effect on the DAO extraction and the effect of the operating temperature and pressure on solvent recovery. The process was designed to contain one extractor, two flash drums, and two steam strippers. The VR was characterized by identifying 15 pseudo-components based on the boiling point distribution, obtained by performing a SIMDIS analysis, and the API gravity of the components. When n-butane was used, the yield of DAO was higher than in the other cases, whereas isobutane showed a similar extraction performance as propane. Solvent recovery was found to increase with temperature and decrease with pressure for all the solvents that were tested and the best results were obtained for propane.
KW - Butane
KW - Numerical Simulation
KW - Propane
KW - Solvent Deasphalting
KW - Solvent Recovery
KW - Vacuum Residue
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U2 - 10.1007/s11814-015-0146-3
DO - 10.1007/s11814-015-0146-3
M3 - Article
AN - SCOPUS:84952630939
SN - 0256-1115
VL - 33
SP - 265
EP - 270
JO - Korean Journal of Chemical Engineering
JF - Korean Journal of Chemical Engineering
IS - 1
ER -