Spin crossover in the cyanide-bridged MoVMnIII single-chain magnet containing FeII cations

Jung Hee Yoon; Dae Won Ryu; Sang Yup Choi; Hyoung Chan Kim; Eui Kwan Koh; Jun Tao; Chang Seop Hong

doi:10.1039/c1cc13627e

Spin crossover in the cyanide-bridged Mo^VMn^III single-chain magnet containing Fe^II cations

Jung Hee Yoon, Dae Won Ryu, Sang Yup Choi, Hyoung Chan Kim, Eui Kwan Koh, Jun Tao, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

A 1D Mo^VMn^III chain compound balanced by {Fe[HC(3,5-Me₂pz)₃]₂}²⁺ dications was prepared. This complex displays a typical single-chain magnet character associated with the Mo^VMn^III chain and a spin crossover phenomenon arising from cationic Fe(ii) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.

Original language	English
Pages (from-to)	10416-10418
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	37
DOIs	https://doi.org/10.1039/c1cc13627e
Publication status	Published - 2011 Oct 7

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc13627e

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abstract = "A 1D MoVMnIII chain compound balanced by {Fe[HC(3,5-Me2pz)3]2}2+ dications was prepared. This complex displays a typical single-chain magnet character associated with the MoVMnIII chain and a spin crossover phenomenon arising from cationic Fe(ii) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.",

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AU - Yoon, Jung Hee

AU - Ryu, Dae Won

AU - Choi, Sang Yup

AU - Kim, Hyoung Chan

AU - Koh, Eui Kwan

AU - Tao, Jun

AU - Hong, Chang Seop

PY - 2011/10/7

Y1 - 2011/10/7

N2 - A 1D MoVMnIII chain compound balanced by {Fe[HC(3,5-Me2pz)3]2}2+ dications was prepared. This complex displays a typical single-chain magnet character associated with the MoVMnIII chain and a spin crossover phenomenon arising from cationic Fe(ii) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.

AB - A 1D MoVMnIII chain compound balanced by {Fe[HC(3,5-Me2pz)3]2}2+ dications was prepared. This complex displays a typical single-chain magnet character associated with the MoVMnIII chain and a spin crossover phenomenon arising from cationic Fe(ii) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.

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Spin crossover in the cyanide-bridged Mo^VMn^III single-chain magnet containing Fe^II cations

Abstract

ASJC Scopus subject areas

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