Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units

Hyun Kim Tae; Hasuck Kim; Hae Lee Joung; Jong Seung Kim

doi:10.5012/bkcs.2008.29.3.620

Sr²⁺ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units

Hyun Kim Tae
, Hasuck Kim
, Hae Lee Joung
, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr²⁺ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca²⁺ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.

Original language	English
Pages (from-to)	620-622
Number of pages	3
Journal	Bulletin of the Korean Chemical Society
Volume	29
Issue number	3
DOIs	https://doi.org/10.5012/bkcs.2008.29.3.620
Publication status	Published - 2008 Mar 20

Keywords

Calixarene
Ion recognition
Strontium
Thiacalixarene
Voltammetry

ASJC Scopus subject areas

General Chemistry

Access to Document

10.5012/bkcs.2008.29.3.620

Cite this

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title = "Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units",

abstract = "A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.",

keywords = "Calixarene, Ion recognition, Strontium, Thiacalixarene, Voltammetry",

author = "Tae, \{Hyun Kim\} and Hasuck Kim and Joung, \{Hae Lee\} and Kim, \{Jong Seung\}",

year = "2008",

month = mar,

day = "20",

doi = "10.5012/bkcs.2008.29.3.620",

language = "English",

volume = "29",

pages = "620--622",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

publisher = "Wiley-Blackwell",

number = "3",

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TY - JOUR

T1 - Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units

AU - Tae, Hyun Kim

AU - Kim, Hasuck

AU - Joung, Hae Lee

AU - Kim, Jong Seung

PY - 2008/3/20

Y1 - 2008/3/20

N2 - A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.

AB - A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.

KW - Calixarene

KW - Ion recognition

KW - Strontium

KW - Thiacalixarene

KW - Voltammetry

UR - https://www.scopus.com/pages/publications/41549129347

U2 - 10.5012/bkcs.2008.29.3.620

DO - 10.5012/bkcs.2008.29.3.620

M3 - Article

AN - SCOPUS:41549129347

SN - 0253-2964

VL - 29

SP - 620

EP - 622

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 3

ER -